Biomass-derived carbon–silicon composites (C@Si) as anodes for lithium-ion and sodium-ion batteries : A promising strategy towards long-term cycling stability : A mini review
Simoes dos Reis, G., Molaiyan, P., Subramaniyam, C. M., García-Alvarado, F., Paolella, A., Pequeno de Oliveira, H., & Lassi, U. (2023). Biomass-derived carbon–silicon composites (C@Si) as anodes for lithium-ion and sodium-ion batteries : A promising strategy towards long-term cycling stability : A mini review. Electrochemistry Communications, 153, Article 107536. https://doi.org/10.1016/j.elecom.2023.107536
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Electrochemistry CommunicationsAuthors
Date
2023Copyright
© 2023 The Author(s). Published by Elsevier B.V.
The global need for high energy density and performing rechargeable batteries has led to the development of high-capacity silicon-based anode materials to meet the energy demands imposed to electrify plug-in vehicles to curtail carbon emissions by 2035. Unfortunately, the high theoretical capacity (4200 mA h g− 1) of silicon by (de-)alloy mechanism is limited by its severe volume changes (ΔV ~ 200% − 400%) during cycling for lithium-ion batteries (LIBs), while for sodium-ion batteries (NIBs) remain uncertain, and hence, compositing with carbons (C@Si) represent a promising strategy to enable the aforementioned practical application. The present review outlines the recent progress of biomass-derived Si-carbon composite (C@Si) anodes for LIBs and NIBs. In this perspective, we present different types of biomass precursors, silicon sources, and compositing strategies, and how these impact on the C@Si physicochemical properties and their electrochemical performance are discussed.
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Elsevier BVISSN Search the Publication Forum
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The content of the publication reflects only the author’s view. The funder is not responsible for any use that may be made of the information it contains.
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Dr. dos Reis thanks Bio4Energy - a Strategic Research Environment appointed by the Swedish government and the Swedish University of Agricultural Sciences, for the funding support. The authors also thank EU/ Interreg Aurora/ GreenBattery project.License
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