dc.contributor.author | Amini, Mohammad | |
dc.contributor.author | Silveira, Orlando J. | |
dc.contributor.author | Vaňo, Viliam | |
dc.contributor.author | Lado, Jose L. | |
dc.contributor.author | Foster, Adam S. | |
dc.contributor.author | Liljeroth, Peter | |
dc.contributor.author | Kezilebieke, Shawulienu | |
dc.date.accessioned | 2023-03-08T07:54:58Z | |
dc.date.available | 2023-03-08T07:54:58Z | |
dc.date.issued | 2023 | |
dc.identifier.citation | Amini, M., Silveira, O. J., Vaňo, V., Lado, J. L., Foster, A. S., Liljeroth, P., & Kezilebieke, S. (2023). Control of Molecular Orbital Ordering Using a van der Waals Monolayer Ferroelectric. <i>Advanced Materials</i>, <i>35</i>(9), 2206456. <a href="https://doi.org/10.1002/adma.202206456" target="_blank">https://doi.org/10.1002/adma.202206456</a> | |
dc.identifier.other | CONVID_164802909 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/85892 | |
dc.description.abstract | Two-dimensional (2D) ferroelectric materials provide a promising platform for the electrical control of quantum states. In particular, due to their 2D nature, they are suitable for influencing the quantum states of deposited molecules via the proximity effect. Here, we report electrically controllable molecular states in phthalocyanine molecules adsorbed on monolayer ferroelectric material SnTe. In particular, we demonstrate that the strain and ferroelectric order in SnTe creates a transition between two distinct orbital orders in the adsorbed phthalocyanine molecules. By controlling the polarization of the ferroelectric domain using scanning tunneling microscopy (STM), we have successfully demonstrated that orbital order can be manipulated electrically. Our results show how ferroelastic coupling in 2D systems allows control of molecular states, providing a starting point for ferroelectrically switchable molecular orbital ordering and ultimately, electrical control of molecular magnetism. | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.publisher | Wiley-VCH Verlag | |
dc.relation.ispartofseries | Advanced Materials | |
dc.rights | CC BY 4.0 | |
dc.title | Control of Molecular Orbital Ordering Using a van der Waals Monolayer Ferroelectric | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202303082053 | |
dc.contributor.laitos | Fysiikan laitos | fi |
dc.contributor.laitos | Department of Physics | en |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 2206456 | |
dc.relation.issn | 0935-9648 | |
dc.relation.numberinseries | 9 | |
dc.relation.volume | 35 | |
dc.type.version | publishedVersion | |
dc.rights.copyright | © 2023 the Authors | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 346654 | |
dc.relation.grantnumber | 338478 | |
dc.relation.grantnumber | 101039500 | |
dc.relation.grantnumber | 101039500 | |
dc.relation.projectid | info:eu-repo/grantAgreement/EC/H2020/101039500/EU//TITAN | |
dc.subject.yso | molekyylielektroniikka | |
dc.subject.yso | sähkökentät | |
dc.subject.yso | molekyylit | |
dc.subject.yso | ohutkalvot | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p21048 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p8138 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p2984 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p16644 | |
dc.rights.url | https://creativecommons.org/licenses/by/4.0/ | |
dc.relation.doi | 10.1002/adma.202206456 | |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | European Commission | en |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Euroopan komissio | fi |
jyx.fundingprogram | Research costs of Academy Research Fellow, AoF | en |
jyx.fundingprogram | Academy Research Fellow, AoF | en |
jyx.fundingprogram | ERC Starting Grant, HE | en |
jyx.fundingprogram | Akatemiatutkijan tutkimuskulut, SA | fi |
jyx.fundingprogram | Akatemiatutkija, SA | fi |
jyx.fundingprogram | ERC Starting Grant, HE | fi |
jyx.fundinginformation | This research made use of the Aalto Nanomicroscopy Center (Aalto NMC) facilities and was supported by the European Research Council (ERC-2021-StG no. 101039500 “Tailoring Quantum Matter on the Flatland” and ERC-2017-AdG no. 788185 “Artificial Designer Materials”) and Academy of Finland (Academy professor funding nos. 318995 and 320555, Academy research fellow nos. 331342, 336243 and no. 338478 and 346654). A.S.F. has been supported by the World Premier International Research Center Initiative (WPI), MEXT, Japan. | |
dc.type.okm | A1 | |