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dc.contributor.authorYu, Shilin
dc.contributor.authorWard, Jas S.
dc.date.accessioned2022-04-06T07:14:50Z
dc.date.available2022-04-06T07:14:50Z
dc.date.issued2022
dc.identifier.citationYu, S., & Ward, J. S. (2022). Ligand exchange among iodine(I) complexes. <i>Dalton Transactions</i>, <i>51</i>(12), 4668-4674. <a href="https://doi.org/10.1039/D1DT04309A" target="_blank">https://doi.org/10.1039/D1DT04309A</a>
dc.identifier.otherCONVID_117609928
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/80506
dc.description.abstractA detailed investigation of ligand exchange between iodine(I) ions in [N⋯I⋯N]+ halogen-bonded complexes is presented. Ligand exchange reactions were conducted to successfully confirm whether iodine(I) complex formation, via the classical [N⋯Ag⋯N]+ to [N⋯I⋯N]+ cation exchange reaction from their analogous Ag+ complexes, could be determined solely by using 1H NMR spectroscopy. In instances where the formation of the iodine(I) complex was unclear or in low yield by the traditional cation exchange reaction, a ligand exchange reaction was used to form the desired iodine(I) complexes in a quantitative manner. Mixing two homoleptic [N⋯I⋯N]+ iodine(I) complexes in 1 : 1 ratio was found to undergo a statistical ligand exchange, with 1H NMR studies showing that the preferred formation of the relative heteroleptic [N1⋯I⋯N2]+ complexes increases with greater differences in the Lewis basicities of two XB acceptors of the complexes involved.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.ispartofseriesDalton Transactions
dc.rightsCC BY 4.0
dc.titleLigand exchange among iodine(I) complexes
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202204062187
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange4668-4674
dc.relation.issn1477-9226
dc.relation.numberinseries12
dc.relation.volume51
dc.type.versionpublishedVersion
dc.rights.copyright© The Royal Society of Chemistry 2022
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber356187
dc.subject.ysokemialliset sidokset
dc.subject.ysokompleksiyhdisteet
dc.subject.ysoligandit
dc.subject.ysohalogeenit
dc.subject.ysojodi
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p10130
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p24741
jyx.subject.urihttp://www.yso.fi/onto/yso/p4164
jyx.subject.urihttp://www.yso.fi/onto/yso/p18902
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1039/D1DT04309A
dc.relation.funderResearch Council of Finlanden
dc.relation.funderSuomen Akatemiafi
jyx.fundingprogramAcademy Research Fellow, AoFen
jyx.fundingprogramAkatemiatutkija, SAfi
jyx.fundinginformationWe gratefully acknowledge ... Magnus Ehrnrooth Foundation (J. S. W.) and the University of Jyvaskyla, Finland for financial support.
dc.type.okmA1


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