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dc.contributor.authorHelmer, Joschua
dc.contributor.authorPakkanen, Olli J.
dc.contributor.authorGendy, Chris
dc.contributor.authorHepp, Alexander
dc.contributor.authorTuononen, Heikki M.
dc.contributor.authorLips, Felicitas
dc.date.accessioned2022-03-17T09:31:15Z
dc.date.available2022-03-17T09:31:15Z
dc.date.issued2022
dc.identifier.citationHelmer, J., Pakkanen, O. J., Gendy, C., Hepp, A., Tuononen, H. M., & Lips, F. (2022). Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C–C bond activation. <i>Chemical Communications</i>, <i>58</i>(21), 3549-3552. <a href="https://doi.org/10.1039/D2CC00298A" target="_blank">https://doi.org/10.1039/D2CC00298A</a>
dc.identifier.otherCONVID_104643627
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/80222
dc.description.abstractReductive debromination of the tribromoamidosilane 2 gave the tetracyclic silaheterocycle 3 through a unique reaction cascade involving unprecedented two-fold intramolecular cycloaddition by transient silylenes. Experimental and computational analyses of the reaction mechanism allowed the identification of the key intermediates that lead to the silaheterocycle 3 or, alternatively, to the cyclotrisilene 19.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.ispartofseriesChemical Communications
dc.rightsCC BY-NC 4.0
dc.titleTetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C–C bond activation
dc.typeresearch article
dc.identifier.urnURN:NBN:fi:jyu-202203171923
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen kemiafi
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineInorganic Chemistryen
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange3549-3552
dc.relation.issn1359-7345
dc.relation.numberinseries21
dc.relation.volume58
dc.type.versionpublishedVersion
dc.rights.copyright© The Royal Society of Chemistry 2022
dc.rights.accesslevelopenAccessfi
dc.type.publicationarticle
dc.relation.grantnumber772510
dc.relation.grantnumber772510
dc.relation.projectidinfo:eu-repo/grantAgreement/EC/H2020/772510/EU//SMAC-MC
dc.subject.ysoheterosykliset yhdisteet
dc.subject.ysokemialliset sidokset
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p38837
jyx.subject.urihttp://www.yso.fi/onto/yso/p10130
dc.rights.urlhttps://creativecommons.org/licenses/by-nc/4.0/
dc.relation.doi10.1039/D2CC00298A
dc.relation.funderEuropean Commissionen
dc.relation.funderEuroopan komissiofi
jyx.fundingprogramERC Consolidator Granten
jyx.fundingprogramERC Consolidator Grantfi
dc.type.okmA1


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