dc.contributor.author | Helmer, Joschua | |
dc.contributor.author | Pakkanen, Olli J. | |
dc.contributor.author | Gendy, Chris | |
dc.contributor.author | Hepp, Alexander | |
dc.contributor.author | Tuononen, Heikki M. | |
dc.contributor.author | Lips, Felicitas | |
dc.date.accessioned | 2022-03-17T09:31:15Z | |
dc.date.available | 2022-03-17T09:31:15Z | |
dc.date.issued | 2022 | |
dc.identifier.citation | Helmer, J., Pakkanen, O. J., Gendy, C., Hepp, A., Tuononen, H. M., & Lips, F. (2022). Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C–C bond activation. <i>Chemical Communications</i>, <i>58</i>(21), 3549-3552. <a href="https://doi.org/10.1039/D2CC00298A" target="_blank">https://doi.org/10.1039/D2CC00298A</a> | |
dc.identifier.other | CONVID_104643627 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/80222 | |
dc.description.abstract | Reductive debromination of the tribromoamidosilane 2 gave the tetracyclic silaheterocycle 3 through a unique reaction cascade involving unprecedented two-fold intramolecular cycloaddition by transient silylenes. Experimental and computational analyses of the reaction mechanism allowed the identification of the key intermediates that lead to the silaheterocycle 3 or, alternatively, to the cyclotrisilene 19. | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.publisher | Royal Society of Chemistry (RSC) | |
dc.relation.ispartofseries | Chemical Communications | |
dc.rights | CC BY-NC 4.0 | |
dc.title | Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C–C bond activation | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202203171923 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen kemia | fi |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Inorganic Chemistry | en |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 3549-3552 | |
dc.relation.issn | 1359-7345 | |
dc.relation.numberinseries | 21 | |
dc.relation.volume | 58 | |
dc.type.version | publishedVersion | |
dc.rights.copyright | © The Royal Society of Chemistry 2022 | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 772510 | |
dc.relation.grantnumber | 772510 | |
dc.relation.projectid | info:eu-repo/grantAgreement/EC/H2020/772510/EU//SMAC-MC | |
dc.subject.yso | heterosykliset yhdisteet | |
dc.subject.yso | kemialliset sidokset | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p38837 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p10130 | |
dc.rights.url | https://creativecommons.org/licenses/by-nc/4.0/ | |
dc.relation.doi | 10.1039/D2CC00298A | |
dc.relation.funder | European Commission | en |
dc.relation.funder | Euroopan komissio | fi |
jyx.fundingprogram | ERC Consolidator Grant | en |
jyx.fundingprogram | ERC Consolidator Grant | fi |
dc.type.okm | A1 | |