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dc.contributor.authorAldridge, Simon
dc.contributor.authorCaise, Alexa
dc.contributor.authorCrumpton, Agamemnon E.
dc.contributor.authorVasko, Petra
dc.contributor.authorHicks, Jamie
dc.contributor.authorMcManus, Caitilín
dc.contributor.authorRees, Nicholas H.
dc.date.accessioned2021-11-29T12:28:13Z
dc.date.available2021-11-29T12:28:13Z
dc.date.issued2022
dc.identifier.citationAldridge, S., Caise, A., Crumpton, A. E., Vasko, P., Hicks, J., McManus, C., & Rees, N. H. (2022). Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi‐Lability. <i>Angewandte Chemie</i>, <i>61</i>(5), Article e202114926. <a href="https://doi.org/10.1002/anie.202114926" target="_blank">https://doi.org/10.1002/anie.202114926</a>
dc.identifier.otherCONVID_101984985
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/78817
dc.description.abstractWe report on the synthesis of a distannyne supported by a pincer ligand bearing pendant amine donors that is capable of reversibly activating E–H bonds at one or both of the tin centres through dissociation of the hemi-labile N–Sn donor/acceptor interactions. This chemistry can be exploited to sequentially (and reversibly) assemble mixed-valence chains of tin atoms of the type ArSn{Sn(Ar)H} n SnAr ( n = 1, 2). The experimentally observed (decreasing) propensity towards chain growth with increasing chain length can be rationalized both thermodynamically and kinetically by the electron-withdrawing properties of the –Sn(Ar)H– backbone units generated via oxidative addition.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofseriesAngewandte Chemie
dc.rightsIn Copyright
dc.subject.othertin
dc.subject.otheroxidative addition
dc.subject.otherreductive elimination
dc.subject.otherhemi-labile ligand
dc.subject.otherreversibility
dc.titleControlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi‐Lability
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202111295822
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen kemiafi
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic Chemistryen
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.relation.issn1433-7851
dc.relation.numberinseries5
dc.relation.volume61
dc.type.versionacceptedVersion
dc.rights.copyright© 2021 Wiley-VCH GmbH
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber314794
dc.subject.ysoligandit
dc.subject.ysotina
dc.subject.ysoorgaaniset tinayhdisteet
dc.subject.ysokemiallinen synteesi
dc.subject.ysokompleksiyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p24741
jyx.subject.urihttp://www.yso.fi/onto/yso/p15916
jyx.subject.urihttp://www.yso.fi/onto/yso/p21052
jyx.subject.urihttp://www.yso.fi/onto/yso/p8468
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/anie.202114926
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramTutkijatohtori, SAfi
jyx.fundingprogramPostdoctoral Researcher, AoFen
jyx.fundinginformationWe thank the Leverhulme Trust and EPSRC for funding. PV would like to thank the Academy of Finland for financial support (project number 314794) and Prof. Heikki M. Tuononen for providing computational resources.


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