dc.contributor.author | Aldridge, Simon | |
dc.contributor.author | Caise, Alexa | |
dc.contributor.author | Crumpton, Agamemnon E. | |
dc.contributor.author | Vasko, Petra | |
dc.contributor.author | Hicks, Jamie | |
dc.contributor.author | McManus, Caitilín | |
dc.contributor.author | Rees, Nicholas H. | |
dc.date.accessioned | 2021-11-29T12:28:13Z | |
dc.date.available | 2021-11-29T12:28:13Z | |
dc.date.issued | 2022 | |
dc.identifier.citation | Aldridge, S., Caise, A., Crumpton, A. E., Vasko, P., Hicks, J., McManus, C., & Rees, N. H. (2022). Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi‐Lability. <i>Angewandte Chemie</i>, <i>61</i>(5), Article e202114926. <a href="https://doi.org/10.1002/anie.202114926" target="_blank">https://doi.org/10.1002/anie.202114926</a> | |
dc.identifier.other | CONVID_101984985 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/78817 | |
dc.description.abstract | We report on the synthesis of a distannyne supported by a pincer ligand bearing pendant amine donors that is capable of reversibly activating E–H bonds at one or both of the tin centres through dissociation of the hemi-labile N–Sn donor/acceptor interactions. This chemistry can be exploited to sequentially (and reversibly) assemble mixed-valence chains of tin atoms of the type ArSn{Sn(Ar)H} n SnAr ( n = 1, 2). The experimentally observed (decreasing) propensity towards chain growth with increasing chain length can be rationalized both thermodynamically and kinetically by the electron-withdrawing properties of the –Sn(Ar)H– backbone units generated via oxidative addition. | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.publisher | Wiley | |
dc.relation.ispartofseries | Angewandte Chemie | |
dc.rights | In Copyright | |
dc.subject.other | tin | |
dc.subject.other | oxidative addition | |
dc.subject.other | reductive elimination | |
dc.subject.other | hemi-labile ligand | |
dc.subject.other | reversibility | |
dc.title | Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi‐Lability | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202111295822 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen kemia | fi |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Inorganic Chemistry | en |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.relation.issn | 1433-7851 | |
dc.relation.numberinseries | 5 | |
dc.relation.volume | 61 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2021 Wiley-VCH GmbH | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 314794 | |
dc.subject.yso | ligandit | |
dc.subject.yso | tina | |
dc.subject.yso | orgaaniset tinayhdisteet | |
dc.subject.yso | kemiallinen synteesi | |
dc.subject.yso | kompleksiyhdisteet | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p24741 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p15916 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p21052 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p8468 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
dc.relation.doi | 10.1002/anie.202114926 | |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Suomen Akatemia | fi |
jyx.fundingprogram | Postdoctoral Researcher, AoF | en |
jyx.fundingprogram | Tutkijatohtori, SA | fi |
jyx.fundinginformation | We thank the Leverhulme Trust and EPSRC for funding. PV would like to thank the Academy of Finland for financial support (project number 314794) and Prof. Heikki M. Tuononen for providing computational resources. | |
dc.type.okm | A1 | |