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dc.contributor.authorRissanen, Kari
dc.contributor.authorTaipale, Essi
dc.contributor.authorTruong, Khai-Nghi
dc.contributor.authorSiepmann, Marcel
dc.date.accessioned2021-10-06T10:37:37Z
dc.date.available2021-10-06T10:37:37Z
dc.date.issued2021
dc.identifier.citationRissanen, K., Taipale, E., Truong, K.-N., & Siepmann, M. (2021). Iodine(I) and Silver(I) Complexes of Benzoimidazole and Pyridylcarbazole Derivatives. <i>Chemistry : A European Journal</i>, <i>27</i>(69), 17412-17419. <a href="https://doi.org/10.1002/chem.202103152" target="_blank">https://doi.org/10.1002/chem.202103152</a>
dc.identifier.otherCONVID_101373181
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/78037
dc.description.abstractThe synthesis of iodine(I) complexes with either benzoimidazole or carbazole-derived sp 2 N -containing Lewis bases is described, as well as their corresponding silver(I) complexes. The addition of elemental iodine to the linear two-coordinate Ag(I) complexes produces iodine(I) complexes with a three-center four-electron (3c-4e) [N — I — N] + bond. The 1 H and 1 H- 15 N HMBC NMR studies unambiguously confirm the formation of the complexes in all cases via the [N — Ag — N] + → [N — I — N] + cation exchange, with the 15 N NMR chemical shift change between 94 to 111 ppm when compared to the free ligand. The single crystal X-ray crystallographic studies on four I + complexes revealed highly symmetrical [N — I — N] + bonds with I — N bond distances of 2.21 - 2.26 Å and N — I — N angles of 177 - 180 ° , whilst some of the corresponding Ag + complexes showed a clear deviation from linearity with N — Ag — N angles of ca. 150 ° and Ag — N bond distances of 2.09 - 2.18 Å.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofseriesChemistry : A European Journal
dc.rightsIn Copyright
dc.subject.otherhalogen(I)
dc.subject.otherhalogen bond
dc.subject.othersupramolecular chemistry
dc.subject.otherNMR
dc.subject.otherX-ray crystallography
dc.titleIodine(I) and Silver(I) Complexes of Benzoimidazole and Pyridylcarbazole Derivatives
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202110065085
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange17412-17419
dc.relation.issn0947-6539
dc.relation.numberinseries69
dc.relation.volume27
dc.type.versionacceptedVersion
dc.rights.copyright© 2021 Wiley-VCH GmbH
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber317259
dc.subject.ysohalogeenit
dc.subject.ysosupramolekulaarinen kemia
dc.subject.ysokemialliset sidokset
dc.subject.ysokompleksiyhdisteet
dc.subject.ysoröntgenkristallografia
dc.subject.ysoNMR-spektroskopia
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p4164
jyx.subject.urihttp://www.yso.fi/onto/yso/p37759
jyx.subject.urihttp://www.yso.fi/onto/yso/p10130
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p29058
jyx.subject.urihttp://www.yso.fi/onto/yso/p26254
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/chem.202103152
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAcademy Project, AoFen
jyx.fundinginformationThe authors gratefully acknowledge the Academy of Finland (K.R. grant no. 317259) and the University of Jyvaskyla, Finland for financial support.


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