Probing the Extremes of Covalency in M–Al bonds : Lithium and Zinc Aluminyl Compounds

Roy, Matthew; Hicks, Jamie; Heilmann, Andreas; Baston, Anne Marie; Vasko, Petra; Goicoechea, Jose; Aldridge, Simon

doi:10.1002/anie.202109416

dc.contributor.author	Roy, Matthew
dc.contributor.author	Hicks, Jamie
dc.contributor.author	Heilmann, Andreas
dc.contributor.author	Baston, Anne Marie
dc.contributor.author	Vasko, Petra
dc.contributor.author	Goicoechea, Jose
dc.contributor.author	Aldridge, Simon
dc.date.accessioned	2021-08-18T05:55:45Z
dc.date.available	2021-08-18T05:55:45Z
dc.date.issued	2021
dc.identifier.citation	Roy, M., Hicks, J., Heilmann, A., Baston, A. M., Vasko, P., Goicoechea, J., & Aldridge, S. (2021). Probing the Extremes of Covalency in M–Al bonds : Lithium and Zinc Aluminyl Compounds. <i>Angewandte Chemie</i>, <i>60</i>(41), 22301-22306. <a href="https://doi.org/10.1002/anie.202109416" target="_blank">https://doi.org/10.1002/anie.202109416</a>
dc.identifier.other	CONVID_99324092
dc.identifier.uri	https://jyx.jyu.fi/handle/123456789/77388
dc.description.abstract	Synthetic routes to lithium, magnesium and zinc aluminyl complexes are reported, allowing for the first structural character-ization of a lithium-aluminium bond. Structural and quantum chemical studies are consistent with the presence of a highly polar Li–Al interaction, characterized by a low bond order and relatively little charge transfer from Al to Li. Comparison with the magnesium and zinc systems reveals changes to both the M–Al bond and the (NON)Al fragment consistent with greater covalent character, with the latter complex being shown to react with CO 2 via a pathway that implies that the zinc centre acts as the nucleophilic partner.	en
dc.format.mimetype	application/pdf
dc.language.iso	eng
dc.publisher	Wiley-VCH Verlag
dc.relation.ispartofseries	Angewandte Chemie
dc.rights	In Copyright
dc.subject.other	aluminium
dc.subject.other	aluminyl
dc.subject.other	low valent compounds
dc.subject.other	lithium
dc.subject.other	zinc
dc.title	Probing the Extremes of Covalency in M–Al bonds : Lithium and Zinc Aluminyl Compounds
dc.type	article
dc.identifier.urn	URN:NBN:fi:jyu-202108184551
dc.contributor.laitos	Kemian laitos	fi
dc.contributor.laitos	Department of Chemistry	en
dc.contributor.oppiaine	Epäorgaaninen kemia	fi
dc.contributor.oppiaine	Epäorgaaninen ja analyyttinen kemia	fi
dc.contributor.oppiaine	Inorganic Chemistry	en
dc.contributor.oppiaine	Inorganic and Analytical Chemistry	en
dc.type.uri	http://purl.org/eprint/type/JournalArticle
dc.type.coar	http://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatus	peerReviewed
dc.format.pagerange	22301-22306
dc.relation.issn	1433-7851
dc.relation.numberinseries	41
dc.relation.volume	60
dc.type.version	acceptedVersion
dc.rights.copyright	© 2021 Wiley
dc.rights.accesslevel	openAccess	fi
dc.relation.grantnumber	314794
dc.subject.yso	sinkki (metallit)
dc.subject.yso	litium
dc.subject.yso	kompleksiyhdisteet
dc.subject.yso	kemialliset sidokset
dc.subject.yso	alumiini
dc.format.content	fulltext
jyx.subject.uri	http://www.yso.fi/onto/yso/p15062
jyx.subject.uri	http://www.yso.fi/onto/yso/p29475
jyx.subject.uri	http://www.yso.fi/onto/yso/p30190
jyx.subject.uri	http://www.yso.fi/onto/yso/p10130
jyx.subject.uri	http://www.yso.fi/onto/yso/p19563
dc.rights.url	http://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi	10.1002/anie.202109416
dc.relation.funder	Research Council of Finland	en
dc.relation.funder	Suomen Akatemia	fi
jyx.fundingprogram	Postdoctoral Researcher, AoF	en
jyx.fundingprogram	Tutkijatohtori, SA	fi
jyx.fundinginformation	We thank the Leverhulme Trust (RP-2018-246) for funding aspects of this work. MMDR thanks the Natural Sciences and Engineering Research Council of Canada (NSERC) for a Postdoctoral Fellowship. PV would like to thank the Academy of Finland for financial support (project number 314794) and Prof. Heikki M. Tuononen for providing computational resources.
dc.type.okm	A1

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Probing the Extremes of Covalency in M–Al bonds : Lithium and Zinc Aluminyl Compounds

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