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dc.contributor.authorRoy, Matthew
dc.contributor.authorHicks, Jamie
dc.contributor.authorHeilmann, Andreas
dc.contributor.authorBaston, Anne Marie
dc.contributor.authorVasko, Petra
dc.contributor.authorGoicoechea, Jose
dc.contributor.authorAldridge, Simon
dc.date.accessioned2021-08-18T05:55:45Z
dc.date.available2021-08-18T05:55:45Z
dc.date.issued2021
dc.identifier.citationRoy, M., Hicks, J., Heilmann, A., Baston, A. M., Vasko, P., Goicoechea, J., & Aldridge, S. (2021). Probing the Extremes of Covalency in M–Al bonds : Lithium and Zinc Aluminyl Compounds. <i>Angewandte Chemie</i>, <i>60</i>(41), 22301-22306. <a href="https://doi.org/10.1002/anie.202109416" target="_blank">https://doi.org/10.1002/anie.202109416</a>
dc.identifier.otherCONVID_99324092
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/77388
dc.description.abstractSynthetic routes to lithium, magnesium and zinc aluminyl complexes are reported, allowing for the first structural character-ization of a lithium-aluminium bond. Structural and quantum chemical studies are consistent with the presence of a highly polar Li–Al interaction, characterized by a low bond order and relatively little charge transfer from Al to Li. Comparison with the magnesium and zinc systems reveals changes to both the M–Al bond and the (NON)Al fragment consistent with greater covalent character, with the latter complex being shown to react with CO 2 via a pathway that implies that the zinc centre acts as the nucleophilic partner.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesAngewandte Chemie
dc.rightsIn Copyright
dc.subject.otheraluminium
dc.subject.otheraluminyl
dc.subject.otherlow valent compounds
dc.subject.otherlithium
dc.subject.otherzinc
dc.titleProbing the Extremes of Covalency in M–Al bonds : Lithium and Zinc Aluminyl Compounds
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202108184551
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen kemiafi
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic Chemistryen
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange22301-22306
dc.relation.issn1433-7851
dc.relation.numberinseries41
dc.relation.volume60
dc.type.versionacceptedVersion
dc.rights.copyright© 2021 Wiley
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber314794
dc.subject.ysosinkki (metallit)
dc.subject.ysolitium
dc.subject.ysokompleksiyhdisteet
dc.subject.ysokemialliset sidokset
dc.subject.ysoalumiini
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p15062
jyx.subject.urihttp://www.yso.fi/onto/yso/p29475
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p10130
jyx.subject.urihttp://www.yso.fi/onto/yso/p19563
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/anie.202109416
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramTutkijatohtori, SAfi
jyx.fundingprogramPostdoctoral Researcher, AoFen
jyx.fundinginformationWe thank the Leverhulme Trust (RP-2018-246) for funding aspects of this work. MMDR thanks the Natural Sciences and Engineering Research Council of Canada (NSERC) for a Postdoctoral Fellowship. PV would like to thank the Academy of Finland for financial support (project number 314794) and Prof. Heikki M. Tuononen for providing computational resources.


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