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dc.contributor.authorJoseph, Jessy
dc.contributor.authorIftekhar, Sidra
dc.contributor.authorSrivastava, Varsha
dc.contributor.authorFallah, Zari
dc.contributor.authorNazarzadeh Zare, Ehsan
dc.contributor.authorSillanpää, Mika
dc.date.accessioned2021-07-01T09:30:58Z
dc.date.available2021-07-01T09:30:58Z
dc.date.issued2021
dc.identifier.citationJoseph, J., Iftekhar, S., Srivastava, V., Fallah, Z., Nazarzadeh Zare, E., & Sillanpää, M. (2021). Iron-based metal-organic framework : Synthesis, structure and current technologies for water reclamation with deep insight into framework integrity. <i>Chemosphere</i>, <i>284</i>, Article 131171. <a href="https://doi.org/10.1016/j.chemosphere.2021.131171" target="_blank">https://doi.org/10.1016/j.chemosphere.2021.131171</a>
dc.identifier.otherCONVID_97861718
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/76941
dc.description.abstractWater is a supreme requirement for the existence of life, the contamination from the point and non-point sources are creating a great threat to the water ecosystem. Advance tools and techniques are required to restore the water quality and metal-organic framework (MOFs) with a tunable porous structure, striking physical and chemical properties are an excellent candidate for it. Fe-based MOFs, which developed rapidly in recent years, are foreseen as most promising to overcome the disadvantages of traditional water depolluting practices. Fe-MOFs with low toxicity and preferable stability possess excellent performance potential for almost all water remedying techniques in contrast to other MOF structures, especially visible light photocatalysis, Fenton, and Fenton-like heterogeneous catalysis. Fe-MOFs become essential tool for water treatment due to their high catalytic activity, abundant active site and pollutant-specific adsorption. However, the structural degradation under external chemical, photolytic, mechanical, and thermal stimuli is impeding Fe-MOFs from further improvement in activity and their commercialization. Understanding the shortcomings of structural integrity is crucial for large-scale synthesis and commercial implementation of Fe-MOFs-based water treatment techniques. Herein we summarize the synthesis, structure and recent advancements in water remediation methods using Fe-MOFs in particular more attention is paid for adsorption, heterogeneous catalysis and photocatalysis with clear insight into the mechanisms involved. For ease of analysis, the pollutants have been classified into two major classes; inorganic pollutants and organic pollutants. In this review, we present for the first time a detailed insight into the challenges in employing Fe-MOFs for water remediation due to structural instability.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherElsevier
dc.relation.ispartofseriesChemosphere
dc.rightsCC BY 4.0
dc.subject.otheriron-based metal-organic framework
dc.subject.othersynthesis
dc.subject.otherstructure
dc.subject.otherwater treatment
dc.subject.otheradsorption
dc.subject.otherfenton degradation
dc.titleIron-based metal-organic framework : Synthesis, structure and current technologies for water reclamation with deep insight into framework integrity
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202107014129
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.relation.issn0045-6535
dc.relation.volume284
dc.type.versionpublishedVersion
dc.rights.copyright© 2021 The Authors. Published by Elsevier Ltd.
dc.rights.accesslevelopenAccessfi
dc.subject.ysoadsorptio
dc.subject.ysorakenne (ominaisuudet)
dc.subject.ysovedenpuhdistus
dc.subject.ysorauta
dc.subject.ysokompleksiyhdisteet
dc.subject.ysokemiallinen synteesi
dc.subject.ysopolymeerit
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p13395
jyx.subject.urihttp://www.yso.fi/onto/yso/p7302
jyx.subject.urihttp://www.yso.fi/onto/yso/p15306
jyx.subject.urihttp://www.yso.fi/onto/yso/p11738
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p8468
jyx.subject.urihttp://www.yso.fi/onto/yso/p926
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1016/j.chemosphere.2021.131171
jyx.fundinginformationThe authors (JJ, VS and MS) acknowledge the funding from the Academy of Finland (decision number 323655).


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