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dc.contributor.authorHossain, Md. Kamal
dc.contributor.authorPlutenko, Maxym O.
dc.contributor.authorSchachner, Jörg A.
dc.contributor.authorHaukka, Matti
dc.contributor.authorMösch-Zanetti, Nadia C.
dc.contributor.authorFritsky, Igor O.
dc.contributor.authorNordlander, Ebbe
dc.date.accessioned2021-04-12T06:32:48Z
dc.date.available2021-04-12T06:32:48Z
dc.date.issued2021
dc.identifier.citationHossain, M. K., Plutenko, M. O., Schachner, J. A., Haukka, M., Mösch-Zanetti, N. C., Fritsky, I. O., & Nordlander, E. (2021). Dioxomolybdenum(VI) complexes of hydrazone phenolate ligands -syntheses and activities in catalytic oxidation reactions. <i>Journal of the Indian Chemical Society</i>, <i>98</i>(2), Article 100006. <a href="https://doi.org/10.1016/j.jics.2021.100006" target="_blank">https://doi.org/10.1016/j.jics.2021.100006</a>
dc.identifier.otherCONVID_51513345
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/75013
dc.description.abstractThe new cis-dioxomolybdenum(VI) complexes [MoO2(L2)(H2O)] (2) and [MoO2(L3) (H2O)] (3) containing the tridentate hydrazone-based ligands (H2L2 = N'-(3,5-di-tert-butyl-2-hydroxybenzylidene)-4-methylbenzohydrazide and H2L3 = N'-(2-hydroxybenzylidene)-2-(hydroxyimino)propanehydrazide) have been synthesised and characterized via IR, 1H and 13C NMR spectroscopy, mass spectrometry, and single crystal X-ray diffraction analysis. The catalytic activities of complexes 2 and 3, and the analogous known complex [MoO2(L1)(H2O)] (1) (H2L1 = N'-(2-hydroxybenzylidene)-4-methylbenzohydrazide) have been evaluated for various oxidation reactions, viz. oxygen atom transfer from dimethyl sulfoxide to triphenylphosphine, and sulfoxidation of methyl-p-tolylsulfide or epoxidation of different alkenes using tert-butyl hydroperoxide as terminal oxidant. The catalytic activities were found to be comparable for all three complexes, but complexes 1 and 3 showed better catalytic performances than complex 2, which contains a more sterically demanding ligand than the other two complexes.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherElsevier B.V.; Indian Chemical Society
dc.relation.ispartofseriesJournal of the Indian Chemical Society
dc.rightsCC BY-NC-ND 4.0
dc.subject.otherdioxomolybdenum(VI) complexes
dc.subject.otherhydrazone
dc.subject.otherschiff base
dc.subject.otheroxidation
dc.subject.otherepoxidation
dc.subject.othersulfoxidation
dc.titleDioxomolybdenum(VI) complexes of hydrazone phenolate ligands -syntheses and activities in catalytic oxidation reactions
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202104122325
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineEpäorgaaninen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineInorganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.relation.issn0019-4522
dc.relation.numberinseries2
dc.relation.volume98
dc.type.versionpublishedVersion
dc.rights.copyright© 2021 Indian Chemical Society
dc.rights.accesslevelopenAccessfi
dc.subject.ysohapetus-pelkistysreaktio
dc.subject.ysokatalyytit
dc.subject.ysokompleksiyhdisteet
dc.subject.ysomolybdeeni
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p28877
jyx.subject.urihttp://www.yso.fi/onto/yso/p15480
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p11107
dc.rights.urlhttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.relation.doi10.1016/j.jics.2021.100006
jyx.fundinginformationThis research has been carried out within the framework of COST Action CM1003 Biological oxidation reactions - mechanisms and design of new catalysts. M.K.H. thanks the European Commission for an Erasmus Mundus predoctoral fellowship. E.N and I.F. thank the Swedish Institute for a joint collaborative grant from the Visby program.


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