Jyväskylän yliopisto | JYX-julkaisuarkisto

 
Näytä aineisto 

Näytä suppeat kuvailutiedot

UV laser induced photolysis of glycolic acid isolated in argon matrices

dc.contributor.authorKrupa, Justy
dc.contributor.authorKosendiak, Iwona
dc.contributor.authorWierzejewska, Maria
dc.contributor.authorAhokas, Jussi
dc.contributor.authorLundell, Jan
dc.date.accessioned2021-03-08T12:11:29Z
dc.date.available2021-03-08T12:11:29Z
dc.date.issued2021
dc.identifier.citationKrupa, J., Kosendiak, I., Wierzejewska, M., Ahokas, J., & Lundell, J. (2021). UV laser induced photolysis of glycolic acid isolated in argon matrices. <i>Journal of Photochemistry and Photobiology A: Chemistry</i>, <i>412</i>, Article 113236. <a href="https://doi.org/10.1016/j.jphotochem.2021.113236" target="_blank">https://doi.org/10.1016/j.jphotochem.2021.113236</a>
dc.identifier.otherCONVID_51760407
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/74528
dc.description.abstractThe photochemistry of matrix-isolated glycolic acid, induced by UV light, was studied by FTIR spectroscopy and B3LYPD3/6-311++G(3df,3pd) calculations. Several decomposition pathways were found to take place upon 212 nm and 226 nm wavelengths irradiation. A number of complexes formed between photoproducts were identified, among them those of formaldehyde with water, carbon monoxide and carbon dioxide as well as the H2O-CO complexes. The structure and spectroscopic assignment of the photoproducts were made comparing the experimental results with the theoretical predictions and available literature data. The observed formation of different complexes indicates various pathways for their formation resulting from UV-induced photodecomposition of different precursor isomers.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherElsevier
dc.relation.ispartofseriesJournal of Photochemistry and Photobiology A: Chemistry
dc.rightsCC BY-NC-ND 4.0
dc.subject.othermolecular complexes
dc.subject.othervibrational spectroscopy
dc.subject.otherMatrix isolation
dc.subject.othercarboxylic acid
dc.subject.othercomputational chemistry
dc.titleUV laser induced photolysis of glycolic acid isolated in argon matrices
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202103081883
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineFysikaalinen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiainePhysical Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.relation.issn1010-6030
dc.relation.volume412
dc.type.versionacceptedVersion
dc.rights.copyright© 2021 Elsevier
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber286844
dc.relation.grantnumber332023
dc.subject.ysospektroskopia
dc.subject.ysomolekyylit
dc.subject.ysovalokemia
dc.subject.ysolaskennallinen kemia
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p10176
jyx.subject.urihttp://www.yso.fi/onto/yso/p2984
jyx.subject.urihttp://www.yso.fi/onto/yso/p7201
jyx.subject.urihttp://www.yso.fi/onto/yso/p23053
dc.rights.urlhttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.relation.doi10.1016/j.jphotochem.2021.113236
dc.relation.funderResearch Council of Finlanden
dc.relation.funderResearch Council of Finlanden
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
jyx.fundingprogramAcademy Project, AoFen
jyx.fundingprogramAcademy Project, AoFen
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundinginformationThe research was supported by Academy of Finland Project No. 286844 and 332023 (at JYU).
dc.type.okmA1


Aineistoon kuuluvat tiedostot

Thumbnail
Nimi:
1-s2.0-S1010603021001088-main.pdf
Koko:
2.238Mb
Tiedostomuoto:
PDF
Kuvaus:
Final Draft
Katso/Avaa

Aineisto kuuluu seuraaviin kokoelmiin

Näytä suppeat kuvailutiedot

CC BY-NC-ND 4.0
Ellei muuten mainita, aineiston lisenssi on CC BY-NC-ND 4.0
Tietosuojailmoitus

Saavutettavuusseloste

Ellei toisin mainittu, julkisesti saatavilla olevia JYX-metatietoja (poislukien tiivistelmät) saa vapaasti uudelleenkäyttää CC0-lisenssillä.