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dc.contributor.authorNonappa
dc.contributor.authorKolehmainen, Erkki
dc.contributor.editorDe Deene, Yves
dc.date.accessioned2020-12-22T06:23:41Z
dc.date.available2020-12-22T06:23:41Z
dc.date.issued2020
dc.identifier.citationNonappa, Kolehmainen, Erkki. (2020). Multinuclear and Solid State NMR of Gels. In Y. De Deene (Ed.), <i>NMR and MRI of Gels</i>. Royal Society of Chemistry. New Developments in NMR, 23. <a href="https://doi.org/10.1039/9781788013178-00200" target="_blank">https://doi.org/10.1039/9781788013178-00200</a>
dc.identifier.otherCONVID_47224792
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/73359
dc.description.abstractOver the past six decades, nuclear magnetic resonance spectroscopy has been an integral part of synthetic organic and organometallic chemistry, as well as biochemistry. Beyond solution state experiments, increasing developments have opened new avenues to study materials in their solid state. Between two extremes (i.e., solution and solid), there exist several other forms of materials, especially soft materials such as gels and liquid crystals. Traditionally gels have been studied using solution state NMR spectroscopic methods. However, the viscosity of complex viscoelastic fluids such as gels affects the molecular tumbling, which in turn affects the chemical shift anisotropy and dipolar and quadrupolar interactions, resulting in broad spectral lines. Therefore, the importance of solid state (SS) NMR in understanding the structural details of self-assembled soft materials has remained unexplored for several decades. Nevertheless, promising results in understanding weak interactions in polymer gels have been explored using solid state cross polarization (CP) and high resolution (HR) magic angle spinning (MAS) NMR spectroscopy. However, similar studies and the possibility to utilize SS NMR spectroscopy to study hydro- and organogels derived from low molecular weight gelators have been limited until recently. In this chapter, we will focus on the application of SS NMR to study xerogels, aerogels and native gels with selected examples.en
dc.format.extent440
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofNMR and MRI of Gels
dc.relation.ispartofseriesNew Developments in NMR
dc.rightsIn Copyright
dc.titleMultinuclear and Solid State NMR of Gels
dc.typebookPart
dc.identifier.urnURN:NBN:fi:jyu-202012227302
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/BookItem
dc.relation.isbn978-1-78801-152-5
dc.description.reviewstatuspeerReviewed
dc.relation.issn2044-253X
dc.type.versionacceptedVersion
dc.rights.copyright© 2020 Royal Society of Chemistry
dc.rights.accesslevelopenAccessfi
dc.subject.ysoNMR-spektroskopia
dc.subject.ysokiinteän olomuodon kemia
dc.subject.ysogeelit
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p26254
jyx.subject.urihttp://www.yso.fi/onto/yso/p18527
jyx.subject.urihttp://www.yso.fi/onto/yso/p12973
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1039/9781788013178-00200


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