Synthesis of novel fluorinated building blocks via halofluorination and related reactions
Remete, A. M., Novák, T. T., Nonn, M., Haukka, M., Fülöp, F., & Kiss, L. (2020). Synthesis of novel fluorinated building blocks via halofluorination and related reactions. Beilstein Journal of Organic Chemistry, 16, 2562-2575. https://doi.org/10.3762/bjoc.16.208
Julkaistu sarjassa
Beilstein Journal of Organic ChemistryPäivämäärä
2020Oppiaine
Epäorgaaninen kemiaEpäorgaaninen ja analyyttinen kemiaInorganic ChemistryInorganic and Analytical ChemistryTekijänoikeudet
© 2020 Remete et al.; licensee Beilstein-Institut
A study exploring halofluorination and fluoroselenation of some cyclic olefins, such as diesters, imides, and lactams with varied functionalization patterns and different structural architectures is described. The synthetic methodologies were based on electrophilic activation through halonium ions of the ring olefin bonds, followed by nucleophilic fluorination with Deoxo-Fluor®. The fluorine-containing products thus obtained were subjected to elimination reactions, yielding various fluorine-containing small-molecular entities.
Julkaisija
Beilstein-Institut zur Förderung der Chemischen WissenschaftenISSN Hae Julkaisufoorumista
2195-951XAsiasanat
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https://converis.jyu.fi/converis/portal/detail/Publication/47123580
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We are grateful to the Hungarian Research Foundation (NKFIH No K 119282) for financial support. Fnancial support of the GINOP-2.3.2-15-2016-00038 project is also acknowledged. This research was supported by the EU-funded Hungarian grant EFOP-3.6.1-16-2016-00008. The Ministry of Human Capacities, Hungary (grant 20391-3/2018/FEKUSTRAT) is also acknowledged.Lisenssi
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