Show simple item record

dc.contributor.authorShen, Hui
dc.contributor.authorXu, Zhen
dc.contributor.authorHazer, Maryam Sabooni Asre
dc.contributor.authorWu, Qingyuan
dc.contributor.authorPeng, Jiang
dc.contributor.authorQin, Ruixuan
dc.contributor.authorMalola, Sami
dc.contributor.authorTeo, Boon K.
dc.contributor.authorHäkkinen, Hannu
dc.contributor.authorZheng, Nanfeng
dc.date.accessioned2020-10-27T09:53:03Z
dc.date.available2020-10-27T09:53:03Z
dc.date.issued2021
dc.identifier.citationShen, H., Xu, Z., Hazer, M. S. A., Wu, Q., Peng, J., Qin, R., Malola, S., Teo, B. K., Häkkinen, H., & Zheng, N. (2021). Surface Coordination of Multiple Ligands Endows N‐Heterocyclic Carbene‐Stabilized Gold Nanoclusters with High Robustness and Surface Reactivity. <i>Angewandte Chemie</i>, <i>60</i>(7), 3752-3758. <a href="https://doi.org/10.1002/anie.202013718" target="_blank">https://doi.org/10.1002/anie.202013718</a>
dc.identifier.otherCONVID_43380073
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/72366
dc.description.abstractDeciphering the molecular pictures of the multi-component and non-periodic organic-inorganic interlayer is a grand technical challenge. Here we show that the atomic arrangement of hybrid surface ligands on metal nanoparticles can be precisely quantified through comprehensive characterization of a novel gold cluster, Au 44 ( i Pr 2 -bimy) 9 (PA) 6 Br 8 , which features three types of ligands, namely, carbene (1,3-diisopropylbenzimidazolin-2-ylidene, i Pr 2 -bimy), alkynyl (phenylacetylide, PA), and halide (Br), respectively. The delicately balanced stereochemical effects and bonding capabilities of the three ligands give rise to peculiar geometrical and electronic structures. Remarkably, despite its complex and highly distorted surface structure, Au 44 ( i Pr 2 -bimy) 9 (PA) 6 Br 8 exhibits unusual catalytic properties and yet it is highly stable, both chemically and thermally. Moreover, rich reactive sites on the cluster surface raise the prospect of bio-compatibility (as it can be functionalized to yield water-soluble derivatives) and bio-applications.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesAngewandte Chemie
dc.rightsIn Copyright
dc.subject.othercluster compounds
dc.subject.othercarbene ligands
dc.subject.othernanostructures
dc.subject.othersurface reactivities
dc.subject.othercatalysis
dc.titleSurface Coordination of Multiple Ligands Endows N‐Heterocyclic Carbene‐Stabilized Gold Nanoclusters with High Robustness and Surface Reactivity
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202010276414
dc.contributor.laitosFysiikan laitosfi
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Physicsen
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineFysikaalinen kemiafi
dc.contributor.oppiaineNanoscience Centeren
dc.contributor.oppiainePhysical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange3752-3758
dc.relation.issn1433-7851
dc.relation.numberinseries7
dc.relation.volume60
dc.type.versionacceptedVersion
dc.rights.copyright© 2020 Wiley
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber292352
dc.relation.grantnumber319208
dc.subject.ysokatalyysi
dc.subject.ysorajapinnat (pinnat)
dc.subject.ysoreaktiivisuus
dc.subject.ysoklusterit
dc.subject.ysonanohiukkaset
dc.subject.ysonanorakenteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p8704
jyx.subject.urihttp://www.yso.fi/onto/yso/p27705
jyx.subject.urihttp://www.yso.fi/onto/yso/p19397
jyx.subject.urihttp://www.yso.fi/onto/yso/p18755
jyx.subject.urihttp://www.yso.fi/onto/yso/p23451
jyx.subject.urihttp://www.yso.fi/onto/yso/p25315
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/anie.202013718
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramAkatemiaprofessorin tehtävä, SAfi
jyx.fundingprogramAkatemiaprofessorin tutkimuskulut, SAfi
jyx.fundingprogramResearch post as Academy Professor, AoFen
jyx.fundingprogramResearch costs of Academy Professor, AoFen
jyx.fundinginformationWe thank the National Key R&D Program of China (2017YFA0207304) and the NNSF of China (21890752, 21731005, 21721001) for financial support. The computational work in the University of Jyväskylä was supported by the Academy of Finland through H. H.’s Academy Professorship (grants 292352 and 319208).


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record

In Copyright
Except where otherwise noted, this item's license is described as In Copyright