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dc.contributor.authorSalojärvi, Esko
dc.contributor.authorPeuronen, Anssi
dc.contributor.authorLahtinen, Manu
dc.contributor.authorHuhtinen, Hannu
dc.contributor.authorVlasenko, Leonid S.
dc.contributor.authorLastusaari, Mika
dc.contributor.authorLehtonen, Ari
dc.date.accessioned2020-06-08T08:40:37Z
dc.date.available2020-06-08T08:40:37Z
dc.date.issued2020
dc.identifier.citationSalojärvi, E., Peuronen, A., Lahtinen, M., Huhtinen, H., Vlasenko, L. S., Lastusaari, M., & Lehtonen, A. (2020). Series of Near-IR-Absorbing Transition Metal Complexes with Redox Active Ligands. <i>Molecules</i>, <i>25</i>(11), Article 2531. <a href="https://doi.org/10.3390/molecules25112531" target="_blank">https://doi.org/10.3390/molecules25112531</a>
dc.identifier.otherCONVID_35868712
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/69762
dc.description.abstractNew soluble and intensely near-IR-absorbing transition metal (Ti, Zr, V, Ni) complexes were synthesized using a redox non-innocent N,N’-bis(3,5-di-tertbutyl-2-hydroxy-phenyl) -1,2-phenylenediamine (H4L) as a ligand precursor. In all the complexes, ([Ti(Lox)2, [Zr(Lox)2], [V(Lsq1)(HLox)] and [Ni(HLox)2], two organic molecules coordinate to the metal center as tri- or tetradentate ligands. The solid-state structures of the complexes were determined using single crystal XRD, and the compounds were further characterized with Electrospray Ionisation Mass Spectrometry (ESI-MS). Thermoanalytical measurements indicated the thermal stabilities of the complexes. All compounds absorb strongly in the near-IR region and show very interesting magnetic and electrochemical properties. Moreover, it was shown that the V and Ni complexes can also convert absorbed near-IR photons to (un)paired electrons, which indicates great promise in photovoltaic applications.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherMDPI
dc.relation.ispartofseriesMolecules
dc.rightsCC BY 4.0
dc.subject.othermetal organic complex
dc.subject.otherredox-active ligand
dc.subject.othernon-innocent ligands
dc.titleSeries of Near-IR-Absorbing Transition Metal Complexes with Redox Active Ligands
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202006084019
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.relation.issn1420-3049
dc.relation.numberinseries11
dc.relation.volume25
dc.type.versionpublishedVersion
dc.rights.copyright© 2020 the Author(s)
dc.rights.accesslevelopenAccessfi
dc.subject.ysoligandit
dc.subject.ysokompleksiyhdisteet
dc.subject.ysoorgaaniset yhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p24741
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p3841
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.3390/molecules25112531
jyx.fundinginformationThis research was funded by the Walther Ahlström foundation and the Magnus Ehrnrooth foundation. A.P. gratefully acknowledges the funding from the Academy of Finland (no. 315911). We gratefully acknowledge the computational resources provided by CSC-IT Center for Science in Finland.


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