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dc.contributor.authorSalojärvi, Esko
dc.contributor.authorPeuronen, Anssi
dc.contributor.authorHuhtinen, Hannu
dc.contributor.authorVlasenko, Leonid S.
dc.contributor.authorHalme, Janne
dc.contributor.authorMäkinen, Pyry
dc.contributor.authorLastusaari, Mika
dc.contributor.authorLehtonen, Ari
dc.date.accessioned2020-04-28T10:09:22Z
dc.date.available2020-04-28T10:09:22Z
dc.date.issued2020
dc.identifier.citationSalojärvi, E., Peuronen, A., Huhtinen, H., Vlasenko, L. S., Halme, J., Mäkinen, P., Lastusaari, M., & Lehtonen, A. (2020). NIR-absorbing transition metal complexes with redox-active ligands. <i>Inorganic Chemistry Communications</i>, <i>112</i>, Article 107711. <a href="https://doi.org/10.1016/j.inoche.2019.107711" target="_blank">https://doi.org/10.1016/j.inoche.2019.107711</a>
dc.identifier.otherCONVID_33762610
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/68742
dc.description.abstractBench top stable transition metal (M = Co, Ni, Cu) complexes with a non-innocent ortho-aminophenol derivative were synthesized by the reaction of metal(II)acetates with a ligand precursor in 2:1 ratio. The solid-state structures reveal the formation of neutral molecular complexes with square planar coordination geometries. The Co(II) and Cu(II) complexes are paramagnetic, whereas the Ni complex is a diamagnetic square planar low-spin Ni(II) complex. All complexes, and Ni(II) complex in particular, show strong absorption in the near-IR region.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherElsevier BV
dc.relation.ispartofseriesInorganic Chemistry Communications
dc.rightsCC BY-NC-ND 4.0
dc.subject.othernon-innocent ligands
dc.subject.othernear-IR absorption
dc.subject.othermetal complexes
dc.subject.otherredox-active ligands
dc.titleNIR-absorbing transition metal complexes with redox-active ligands
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202004282947
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.relation.issn1387-7003
dc.relation.volume112
dc.type.versionacceptedVersion
dc.rights.copyright© 2019 Elsevier B.V. All rights reserved.
dc.rights.accesslevelopenAccessfi
dc.subject.ysoligandit
dc.subject.ysokompleksiyhdisteet
dc.subject.ysoinfrapunasäteily
dc.subject.ysoabsorptio
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p24741
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p7126
jyx.subject.urihttp://www.yso.fi/onto/yso/p4151
dc.rights.urlhttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.relation.doi10.1016/j.inoche.2019.107711
jyx.fundinginformationES wishes to thank the Magnus Ehrnrooth foundation for the financial support. AP is grateful for the financial support by the Academy of Finland (project no. 315911).


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