NIR-absorbing transition metal complexes with redox-active ligands
| dc.contributor.author | Salojärvi, Esko | |
| dc.contributor.author | Peuronen, Anssi | |
| dc.contributor.author | Huhtinen, Hannu | |
| dc.contributor.author | Vlasenko, Leonid S. | |
| dc.contributor.author | Halme, Janne | |
| dc.contributor.author | Mäkinen, Pyry | |
| dc.contributor.author | Lastusaari, Mika | |
| dc.contributor.author | Lehtonen, Ari | |
| dc.date.accessioned | 2020-04-28T10:09:22Z | |
| dc.date.available | 2020-04-28T10:09:22Z | |
| dc.date.issued | 2020 | |
| dc.identifier.citation | Salojärvi, E., Peuronen, A., Huhtinen, H., Vlasenko, L. S., Halme, J., Mäkinen, P., Lastusaari, M., & Lehtonen, A. (2020). NIR-absorbing transition metal complexes with redox-active ligands. <i>Inorganic Chemistry Communications</i>, <i>112</i>, Article 107711. <a href="https://doi.org/10.1016/j.inoche.2019.107711" target="_blank">https://doi.org/10.1016/j.inoche.2019.107711</a> | |
| dc.identifier.other | CONVID_33762610 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/68742 | |
| dc.description.abstract | Bench top stable transition metal (M = Co, Ni, Cu) complexes with a non-innocent ortho-aminophenol derivative were synthesized by the reaction of metal(II)acetates with a ligand precursor in 2:1 ratio. The solid-state structures reveal the formation of neutral molecular complexes with square planar coordination geometries. The Co(II) and Cu(II) complexes are paramagnetic, whereas the Ni complex is a diamagnetic square planar low-spin Ni(II) complex. All complexes, and Ni(II) complex in particular, show strong absorption in the near-IR region. | en |
| dc.format.mimetype | application/pdf | |
| dc.language | eng | |
| dc.language.iso | eng | |
| dc.publisher | Elsevier BV | |
| dc.relation.ispartofseries | Inorganic Chemistry Communications | |
| dc.rights | CC BY-NC-ND 4.0 | |
| dc.subject.other | non-innocent ligands | |
| dc.subject.other | near-IR absorption | |
| dc.subject.other | metal complexes | |
| dc.subject.other | redox-active ligands | |
| dc.title | NIR-absorbing transition metal complexes with redox-active ligands | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202004282947 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.relation.issn | 1387-7003 | |
| dc.relation.volume | 112 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © 2019 Elsevier B.V. All rights reserved. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.subject.yso | ligandit | |
| dc.subject.yso | kompleksiyhdisteet | |
| dc.subject.yso | infrapunasäteily | |
| dc.subject.yso | absorptio | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p24741 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p7126 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p4151 | |
| dc.rights.url | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.relation.doi | 10.1016/j.inoche.2019.107711 | |
| jyx.fundinginformation | ES wishes to thank the Magnus Ehrnrooth foundation for the financial support. AP is grateful for the financial support by the Academy of Finland (project no. 315911). | |
| dc.type.okm | A1 |
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