dc.contributor.author | Salonen, Pasi, Peuronen, Anssi | |
dc.contributor.author | Lehtonen, Ari | |
dc.date.accessioned | 2020-04-27T11:32:48Z | |
dc.date.available | 2020-04-27T11:32:48Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Salonen, P., & Lehtonen, A. (2020). Bioinspired Mo, W and V complexes bearing a highly hydroxyl-functionalized Schiff base ligand. <i>Inorganica Chimica Acta</i>, <i>503</i>, Article 119414. <a href="https://doi.org/10.1016/j.ica.2020.119414" target="_blank">https://doi.org/10.1016/j.ica.2020.119414</a> | |
dc.identifier.other | CONVID_34071258 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/68718 | |
dc.description.abstract | A series of bioinspired dioxidomolybdenum(vi), dioxidotungsten(vi) and oxidovanadium(v) complexes [MoO2(H2LSaltris)], [WO2(H2LSaltris)] and [VO(HLSaltris)]2 were prepared by the reaction of a hydroxyl-rich Schiff base proligand N-(1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)-3,5-di-tert-butylsalicylaldimine (H4LSaltris) with metal precursors in methanol solutions. Molybdenum and tungsten complexes crystallize as mononuclear molecules, whereas the vanadium complex forms dinuclear units. From the complexes, [VO(HLSaltris)]2 shows activity in the oxidation of 4-tert-butylcatechol and 3,5-di-tert-butylcatechol, mimicking the action of the dicopper enzyme catechol oxidase. | en |
dc.format.mimetype | application/pdf | |
dc.language | eng | |
dc.language.iso | eng | |
dc.publisher | Elsevier BV | |
dc.relation.ispartofseries | Inorganica Chimica Acta | |
dc.rights | In Copyright | |
dc.subject.other | inorganic chemistry | |
dc.title | Bioinspired Mo, W and V complexes bearing a highly hydroxyl-functionalized Schiff base ligand | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202004272917 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.relation.issn | 0020-1693 | |
dc.relation.volume | 503 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2020 Elsevier B.V. | |
dc.rights.accesslevel | openAccess | fi |
dc.subject.yso | epäorgaaninen kemia | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p1800 | |
dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
dc.relation.doi | 10.1016/j.ica.2020.119414 | |
jyx.fundinginformation | AP gratefully acknowledges the Academy of Finland for funding (grant no. 315911). PS greatly acknowledges the University of Turku Graduate School (UTUGS) Doctoral Programme in Physical and Chemical Sciences (PCS) for funding. | |
dc.type.okm | A1 | |