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dc.contributor.authorHicks, Jamie
dc.contributor.authorHeilmann, Andreas
dc.contributor.authorVasko, Petra
dc.contributor.authorGoicoechea, Jose
dc.contributor.authorAldridge, Simon
dc.date.accessioned2019-10-11T12:14:43Z
dc.date.available2019-10-11T12:14:43Z
dc.date.issued2019
dc.identifier.citationHicks, J., Heilmann, A., Vasko, P., Goicoechea, J., & Aldridge, S. (2019). Trapping and Reactivity of a Molecular Aluminium Oxide Ion. <i>Angewandte Chemie</i>, <i>131</i>(48), 17425-17428. <a href="https://doi.org/10.1002/ange.201910509" target="_blank">https://doi.org/10.1002/ange.201910509</a>
dc.identifier.otherCONVID_33015883
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/65829
dc.description.abstractAluminium oxides constitute an important class of inorganic compound that are widely exploited in the chemical industry as catalysts and catalyst supports. Due to the tendency for such systems to aggregate via Al‐O‐Al bridges, the synthesis of well‐defined, soluble, molecular models for these materials is challenging. Here we show that reactions of the potassium aluminyl complex K 2 [( NON )Al] 2 ( NON = 4,5‐bis(2,6‐diiso‐propylanilido)‐2,7‐di‐tert‐butyl‐9,9‐dimethylxanthene) with CO 2 , PhNCO and N 2 O all proceed via a common aluminium oxide intermediate. This highly reactive species can be trapped by coordination of a THF molecule as the anionic oxide complex [( NON )AlO(THF)] ‐ , which features discrete Al‐O bonds and dimerizes in the solid state via weak O … K interactions. This species reacts with a range of small molecules including N 2 O to give a hyponitrite ([N 2 O 2 ] 2‐ ) complex and H 2 , the latter offering an unequivocal example of heterolytic E‐H bond cleavage across a main group M‐O bond.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesAngewandte Chemie
dc.rightsIn Copyright
dc.subject.otheraluminium
dc.subject.otheroxide
dc.subject.otheraluminyl
dc.subject.otherreduction
dc.subject.othersmall molecule activation
dc.titleTrapping and Reactivity of a Molecular Aluminium Oxide Ion
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201910114407
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange17425-17428
dc.relation.issn1433-7851
dc.relation.numberinseries48
dc.relation.volume131
dc.type.versionacceptedVersion
dc.rights.copyright© 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber314794
dc.subject.ysoalumiini
dc.subject.ysooksidit
dc.subject.ysokompleksiyhdisteet
dc.subject.ysopelkistys
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p19563
jyx.subject.urihttp://www.yso.fi/onto/yso/p2803
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p9117
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/ange.201910509
dc.relation.funderSuomen Akatemiafi
dc.relation.funderResearch Council of Finlanden
jyx.fundingprogramTutkijatohtori, SAfi
jyx.fundingprogramPostdoctoral Researcher, AoFen
dc.type.okmA1


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