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dc.contributor.authorGuo, Fu-Sheng
dc.contributor.authorChen, Yan-Cong
dc.contributor.authorTong, Ming-Liang
dc.contributor.authorMansikkamäki, Akseli
dc.contributor.authorLayfield, Richard
dc.date.accessioned2019-08-23T11:44:15Z
dc.date.available2020-04-30T21:35:12Z
dc.date.issued2019
dc.identifier.citationGuo, F.-S., Chen, Y.-C., Tong, M.-L., Mansikkamäki, A., & Layfield, R. (2019). Uranocenium : Synthesis, Structure and Chemical Bonding. <i>Angewandte Chemie</i>, <i>58</i>(30), 10163-10167. <a href="https://doi.org/10.1002/ange.201903681" target="_blank">https://doi.org/10.1002/ange.201903681</a>
dc.identifier.otherCONVID_30609747
dc.identifier.otherTUTKAID_81352
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/65290
dc.description.abstractAbstraction of iodide from [(η5‐C5iPr5)2UI] (1) produced the cationic uranium(III) metallocene [(η5‐C5iPr5)2U]+ (2) as a salt of [B(C6F5)4]−. The structure of 2 consists of unsymmetrically bonded cyclopentadienyl ligands and a bending angle of 167.82° at uranium. Analysis of the bonding in 2 showed that the uranium 5f orbitals are strongly split and mixed with the ligand orbitals, thus leading to non‐negligible covalent contributions to the bonding. Investigation of the dynamic magnetic properties of 2 revealed that the 5f covalency leads to partially quenched anisotropy and fast magnetic relaxation in zero applied magnetic field. Application of a magnetic field leads to dominant relaxation by a Raman process.fi
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley - VCH Verlag GmbH & Co. KGaA
dc.relation.ispartofseriesAngewandte Chemie
dc.rightsIn Copyright
dc.subject.otherchemical bonding
dc.subject.otherelectronic structure
dc.subject.othermetallocenes
dc.titleUranocenium : Synthesis, Structure and Chemical Bonding
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201908223873
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2019-08-22T09:15:24Z
dc.description.reviewstatuspeerReviewed
dc.format.pagerange10163-10167
dc.relation.issn1433-7851
dc.relation.numberinseries30
dc.relation.volume58
dc.type.versionacceptedVersion
dc.rights.copyright© 2019 Wiley‐VCH Verlag GmbH & Co.
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber289172
dc.subject.ysoorganometalliyhdisteet
dc.subject.ysouraani
dc.subject.ysokemiallinen synteesi
dc.subject.ysokemialliset sidokset
dc.subject.ysomagneettiset ominaisuudet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p28123
jyx.subject.urihttp://www.yso.fi/onto/yso/p11691
jyx.subject.urihttp://www.yso.fi/onto/yso/p8468
jyx.subject.urihttp://www.yso.fi/onto/yso/p10130
jyx.subject.urihttp://www.yso.fi/onto/yso/p597
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/ange.201903681
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAcademy Project, AoFen
jyx.fundinginformationWe thank the ERC (CoG 646740), the EPSRC (EP/M022064/1), the NSF China (projects 21620102002, 91422302), the National Key Research and Development Program of China (2018YFA0306001), the Magnus Ehrnrooth Foundation, the Academy of Finland (project 289172), the CSC-IT Center for Science in Finland, the Finnish Grid and Cloud Infrastructure (urn:nbn:fi:research-infras-2016072533),


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