Näytä suppeat kuvailutiedot

dc.contributor.authorWarzok, Ulrike
dc.contributor.authorMarianski, Mateusz
dc.contributor.authorHoffmann, Waldemar
dc.contributor.authorTurunen, Lotta
dc.contributor.authorRissanen, Kari
dc.contributor.authorPagel, Kevin
dc.contributor.authorSchalley, Christoph A.
dc.date.accessioned2018-11-16T09:32:18Z
dc.date.available2018-11-16T09:32:18Z
dc.date.issued2018
dc.identifier.citationWarzok, U., Marianski, M., Hoffmann, W., Turunen, L., Rissanen, K., Pagel, K., & Schalley, C. A. (2018). Surprising solvent-induced structural rearrangements in large [N⋯I+⋯N] halogen-bonded supramolecular capsules : an ion mobility-mass spectrometry study. <i>Chemical Science</i>, <i>9</i>(44), 8343-8351. <a href="https://doi.org/10.1039/C8SC03040E" target="_blank">https://doi.org/10.1039/C8SC03040E</a>
dc.identifier.otherCONVID_28274679
dc.identifier.otherTUTKAID_78907
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/60211
dc.description.abstractCoordinative halogen bonds have recently gained interest for the assembly of supramolecular capsules. Ion mobility-mass spectrometry and theoretical calculations now reveal the well-defined gas-phase structures of dimeric and hexameric [N/I +/N] halogen-bonded capsules with counterions located inside their cavities as guests. The solution reactivity of the large hexameric capsule shows the intriguing solventdependent equilibrium between the hexamer and an unprecedented pentameric [N/I +/N] halogenbonded capsule, when the solvent is changed from chloroform to dichloromethane. The intrinsic flexibility of the cavitands enables this novel structure to adopt a pseudo-trigonal bipyramidal geometry with nine [N/I +/N] bonds along the edges and two pyridine binding sites uncomplexed.fi
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofseriesChemical Science
dc.rightsCC BY-NC 4.0
dc.subject.otherhalogen-bonded supramolecular capsules
dc.subject.otherion mobility-mass
dc.subject.otherspectrometry study
dc.titleSurprising solvent-induced structural rearrangements in large [N⋯I+⋯N] halogen-bonded supramolecular capsules : an ion mobility-mass spectrometry study
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201811154734
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-11-15T13:15:16Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange8343-8351
dc.relation.issn2041-6520
dc.relation.numberinseries44
dc.relation.volume9
dc.type.versionpublishedVersion
dc.rights.copyright© the Authors, 2018.
dc.rights.accesslevelopenAccessfi
dc.subject.ysosupramolekulaarinen kemia
dc.subject.ysospektrometria
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p37759
jyx.subject.urihttp://www.yso.fi/onto/yso/p10177
dc.rights.urlhttps://creativecommons.org/licenses/by-nc/4.0/
dc.relation.doi10.1039/C8SC03040E
dc.type.okmA1


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