Show simple item record

dc.contributor.authorWarzok, Ulrike
dc.contributor.authorMarianski, Mateusz
dc.contributor.authorHoffmann, Waldemar
dc.contributor.authorTurunen, Lotta
dc.contributor.authorRissanen, Kari
dc.contributor.authorPagel, Kevin
dc.contributor.authorSchalley, Christoph A.
dc.date.accessioned2018-11-16T09:32:18Z
dc.date.available2018-11-16T09:32:18Z
dc.date.issued2018fi
dc.identifier.citationWarzok, U., Marianski, M., Hoffmann, W., Turunen, L., Rissanen, K., Pagel, K., & Schalley, C. A. (2018). Surprising solvent-induced structural rearrangements in large [N⋯I+⋯N] halogen-bonded supramolecular capsules : an ion mobility-mass spectrometry study. <em>Chemical Science</em>, 9 (44), 8343-8351. <a href="https://doi.org/10.1039/C8SC03040E">doi:10.1039/C8SC03040E</a>fi
dc.identifier.otherTUTKAID_78907
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/60211
dc.description.abstractCoordinative halogen bonds have recently gained interest for the assembly of supramolecular capsules. Ion mobility-mass spectrometry and theoretical calculations now reveal the well-defined gas-phase structures of dimeric and hexameric [N/I +/N] halogen-bonded capsules with counterions located inside their cavities as guests. The solution reactivity of the large hexameric capsule shows the intriguing solventdependent equilibrium between the hexamer and an unprecedented pentameric [N/I +/N] halogenbonded capsule, when the solvent is changed from chloroform to dichloromethane. The intrinsic flexibility of the cavitands enables this novel structure to adopt a pseudo-trigonal bipyramidal geometry with nine [N/I +/N] bonds along the edges and two pyridine binding sites uncomplexed.fi
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofseriesChemical Science
dc.rightsCC BY-NC 4.0
dc.subject.otherhalogeenisidoksetfi
dc.subject.othersupramolekulaarinen kemiafi
dc.subject.otherspektrometriafi
dc.subject.otherhalogen-bonded supramolecular capsulesfi
dc.subject.otherion mobility-massfi
dc.subject.otherspectrometry studyfi
dc.titleSurprising solvent-induced structural rearrangements in large [N⋯I+⋯N] halogen-bonded supramolecular capsules : an ion mobility-mass spectrometry studyfi
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201811154734
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-11-15T13:15:16Z
dc.description.reviewstatuspeerReviewed
dc.format.pagerange8343-8351
dc.relation.issn2041-6520
dc.relation.numberinseries44
dc.relation.volume9
dc.type.versionPublisher's PDF
dc.rights.copyright© the Authors, 2018.
dc.rights.accesslevelopenAccessfi
dc.format.contentfulltext
dc.rights.urlhttps://creativecommons.org/licenses/by-nc/4.0/
dc.relation.doi10.1039/C8SC03040E


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record

CC BY-NC 4.0
Except where otherwise noted, this item's license is described as CC BY-NC 4.0