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dc.contributor.authorMäkelä, Eveliina
dc.contributor.authorLahti, Riikka
dc.contributor.authorJaatinen, Salla
dc.contributor.authorRomar, Henrik
dc.contributor.authorHu, Tao
dc.contributor.authorPuurunen, Riikka L.
dc.contributor.authorLassi, Ulla
dc.contributor.authorKarinen, Reetta
dc.date.accessioned2018-11-12T06:36:14Z
dc.date.available2019-04-25T21:35:18Z
dc.date.issued2018
dc.identifier.citationMäkelä, E., Lahti, R., Jaatinen, S., Romar, H., Hu, T., Puurunen, R. L., Lassi, U., & Karinen, R. (2018). Study of Ni, Pt, and Ru Catalysts on Wood-based Activated Carbon Supports and their Activity in Furfural Conversion to 2-Methylfuran. <i>ChemCatChem</i>, <i>10</i>(15), 3269-3283. <a href="https://doi.org/10.1002/cctc.201800263" target="_blank">https://doi.org/10.1002/cctc.201800263</a>
dc.identifier.otherCONVID_28121239
dc.identifier.otherTUTKAID_78015
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/60174
dc.description.abstractBio‐based chemicals can be produced from furfural through hydrotreatment. In this study, 2‐methylfuran (MF), a potential biofuel component, was produced with Pt, Ru, and Ni catalysts supported on wood‐based activated carbons. The catalytic hydrotreatment experiments were conducted in a batch reactor at 210–240 °C with 2‐propanol as solvent and 40 bar H2 pressure. Two types of activated carbon supports were prepared by carbonization and activation of lignocellulosic biomass (forest‐residue‐based birch and spruce from Finland). Both types of activated carbons were suitable as catalyst supports, giving up to 100 % furfural conversions. The most important factors affecting the MF yield were the metal dispersion and particle size as well as reaction temperature. The highest observed MF yields were achieved with the noble metal catalysts with the highest dispersions at 240 °C after 120 min reaction time: 3 wt % Pt on spruce (MF yield of 50 %) and 3 wt % Ru on birch (MF yield of 49 %). Nickel catalysts were less active most likely owing to lower dispersions and incomplete metal reduction. Interesting results were obtained also with varying the metal loadings: the lower Pt loading (1.5 wt %) achieved almost the same MF yield as the 3 wt % catalysts, which can enable the production of MF with high yields and reduced catalyst costs. Based on this study, biomass‐based renewable activated carbons can be used as catalyst supports in furfural hydrotreatment with high conversions.fi
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.ispartofseriesChemCatChem
dc.rightsIn Copyright
dc.subject.other2-methylfuran
dc.subject.otherbiofuel
dc.titleStudy of Ni, Pt, and Ru Catalysts on Wood-based Activated Carbon Supports and their Activity in Furfural Conversion to 2-Methylfuran
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201811074647
dc.contributor.laitosKokkolan yliopistokeskus Chydeniusfi
dc.contributor.laitosKokkola University Consortium Chydeniusen
dc.contributor.oppiaineSoveltavan kemian yksikköfi
dc.contributor.oppiaineThe Unit of Applied Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-11-07T13:15:08Z
dc.description.reviewstatuspeerReviewed
dc.format.pagerange3269-3283
dc.relation.issn1867-3880
dc.relation.numberinseries15
dc.relation.volume10
dc.type.versionacceptedVersion
dc.rights.copyright© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
dc.rights.accesslevelopenAccessfi
dc.subject.ysobiokemikaalit
dc.subject.ysofuraanit
dc.subject.ysofurfuraali
dc.subject.ysokatalyytit
dc.subject.ysometallit
dc.subject.ysoaktiivihiili
dc.subject.ysobiomassa (teollisuus)
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p27307
jyx.subject.urihttp://www.yso.fi/onto/yso/p7657
jyx.subject.urihttp://www.yso.fi/onto/yso/p28979
jyx.subject.urihttp://www.yso.fi/onto/yso/p15480
jyx.subject.urihttp://www.yso.fi/onto/yso/p3097
jyx.subject.urihttp://www.yso.fi/onto/yso/p25569
jyx.subject.urihttp://www.yso.fi/onto/yso/p6170
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/cctc.201800263


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