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dc.contributor.authorGroenhof, Gerrit
dc.contributor.authorToppari, Jussi
dc.date.accessioned2018-09-19T07:18:40Z
dc.date.available2018-09-19T07:18:40Z
dc.date.issued2018
dc.identifier.citationGroenhof, Gerrit; Toppari, Jussi (2018). Coherent Light Harvesting through Strong Coupling to Confined Light. Journal of Physical Chemistry Letters, 9 (17), 4848-4851. DOI: 10.1021/acs.jpclett.8b02032
dc.identifier.otherCONVID_28214085
dc.identifier.otherTUTKAID_78541
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/59566
dc.description.abstractWhen photoactive molecules interact strongly with confined light modes, new hybrid light-matter states may form: the polaritons. These polaritons are coherent superpositions of excitations of the molecules and of the cavity photon. Recently, polaritons were shown to mediate energy transfer between chromophores at distances beyond the Förster limit. Here we explore the potential of strong coupling for light-harvesting applications by means of atomistic molecular dynamics simulations of mixtures of photoreactive and non-photo-reactive molecules strongly coupled to a single confined light mode. These molecules are spatially separated and present at different concentrations. Our simulations suggest that while the excitation is initially fully delocalized over all molecules and the confined light mode, it very rapidly localizes onto one of the photoreactive molecules, which then undergoes the reaction.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesJournal of Physical Chemistry Letters
dc.rightsCC BY 4.0
dc.subject.othercoherent light harvesting
dc.subject.otherstrong coupling
dc.subject.otherconfined light
dc.titleCoherent Light Harvesting through Strong Coupling to Confined Light
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201809074042
dc.contributor.laitosFysiikan laitosfi
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Physicsen
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineFysikaalinen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiainePhysical Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-09-07T09:15:12Z
dc.description.reviewstatuspeerReviewed
dc.format.pagerange4848-4851
dc.relation.issn1948-7185
dc.relation.numberinseries17
dc.relation.volume9
dc.type.versionpublishedVersion
dc.rights.copyright© 2018 American Chemical Society
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber289947
dc.relation.grantnumber290677
dc.subject.ysovalokemia
dc.subject.ysopolaritonit
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p7201
jyx.subject.urihttp://www.yso.fi/onto/yso/p38894
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1021/acs.jpclett.8b02032
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAcademy Project, AoFen
jyx.fundingprogramAcademy Project, AoFen
jyx.fundinginformationThis work was supported by the Academy of Finland (grants 290677 to G.G. and 289947 to J.J.T.).


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