dc.contributor.author | Lasri, Jamal | |
dc.contributor.author | Elsherbiny, Abeer S. | |
dc.contributor.author | Eltayeb, Naser Eltaher | |
dc.contributor.author | Haukka, Matti | |
dc.contributor.author | El-Hefnawy, Mohamed E. | |
dc.date.accessioned | 2018-04-13T09:44:49Z | |
dc.date.available | 2020-06-01T21:35:12Z | |
dc.date.issued | 2018 | |
dc.identifier.citation | Lasri, J., Elsherbiny, A. S., Eltayeb, N. E., Haukka, M., & El-Hefnawy, M. E. (2018). Synthesis and characterization of ferrocene-based Schiff base and ferrocenecarboxaldehyde oxime and their adsorptive removal of methyl blue from aqueous solution. <i>Journal of Organometallic Chemistry</i>, <i>866</i>, 21-26. <a href="https://doi.org/10.1016/j.jorganchem.2018.04.004" target="_blank">https://doi.org/10.1016/j.jorganchem.2018.04.004</a> | |
dc.identifier.other | CONVID_27986971 | |
dc.identifier.other | TUTKAID_77280 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/57585 | |
dc.description.abstract | The ferrocene-based Schiff base 3 was synthetized by reaction of ferrocenecarboxaldehyde 1 with 4-aminoantipyrine 2. However, the reaction of 1 with hydroxylamine affords ferrocenecarboxaldehyde oxime 4. Compounds 3 and 4 were fully characterized by IR, 1H, 13C and DEPT-135 NMR spectroscopy, elemental analyses and also by single crystal X-ray diffraction. Compounds 3 and 4 were used to remove anionic methyl blue dye from wastewater. The results established that both compounds have high adsorption capacity towards methyl blue. Langmuir adsorption capacity of compound 4 (464 mmol/g) is much higher than that of compound 3 (193 mmol/g) at 25 °C. The kinetics data was fitted well pseudo-second-order model. Thermodynamic studies show that the adsorption of methyl blue onto compound 3 was endothermic, while its exothermic in case of adsorption onto compound 4. The process was spontaneous for both compounds. | |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.publisher | Elsevier BV | |
dc.relation.ispartofseries | Journal of Organometallic Chemistry | |
dc.subject.other | ferrocene-based Schiff base | |
dc.subject.other | ferrocenecarboxaldehyde oxime | |
dc.subject.other | single crystal X-ray diffraction | |
dc.subject.other | methyl blue dye | |
dc.title | Synthesis and characterization of ferrocene-based Schiff base and ferrocenecarboxaldehyde oxime and their adsorptive removal of methyl blue from aqueous solution | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201804112030 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2018-04-11T12:19:58Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 21-26 | |
dc.relation.issn | 0022-328X | |
dc.relation.numberinseries | 0 | |
dc.relation.volume | 866 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2018 Elsevier B.V. This is a final draft version of an article whose final and definitive form has been published by Elsevier B.V. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.subject.yso | adsorptio | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p13395 | |
dc.relation.doi | 10.1016/j.jorganchem.2018.04.004 | |
dc.type.okm | A1 | |