| dc.contributor.author | Karhu, Aino J. | |
| dc.contributor.author | Jämsä, Juho | |
| dc.contributor.author | Rautiainen, J. Mikko | |
| dc.contributor.author | Oilunkaniemi, Raija | |
| dc.contributor.author | Chivers, Tristram | |
| dc.contributor.author | Laitinen, Risto S. | |
| dc.date.accessioned | 2018-01-17T13:21:05Z | |
| dc.date.available | 2018-03-16T22:45:12Z | |
| dc.date.issued | 2017 | |
| dc.identifier.citation | Karhu, A. J., Jämsä, J., Rautiainen, J. M., Oilunkaniemi, R., Chivers, T., & Laitinen, R. S. (2017). A Selenium-Nitrogen Chain with Selenium in Different Oxidation States. <i>Zeitschrift für anorganische und allgemeine Chemie</i>, <i>643</i>(7), 495-500. <a href="https://doi.org/10.1002/zaac.201700031" target="_blank">https://doi.org/10.1002/zaac.201700031</a> | |
| dc.identifier.other | CONVID_26913809 | |
| dc.identifier.other | TUTKAID_73293 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/56771 | |
| dc.description.abstract | The reaction of tBuNH2 with a mixture of SeCl2 and SeOCl2 in a 6:2:1 molar ratio produces the novel selenium-nitrogen chain ClSeN(tBu)Se(O)Cl (4), in which the selenium atoms are in two different oxidation states, SeII and SeIV. The crystal structure of 4 is compared with that of the related SeII/SeII system ClSeN(tBu)SeCl (1) and differences are attributed to hyperconjugative effects. The energetics of the formation of 4 via two different routes are elucidated by PBE0/def2-TZVPP calculations. | |
| dc.language.iso | eng | |
| dc.publisher | Wiley-VCH-Verlag | |
| dc.relation.ispartofseries | Zeitschrift für anorganische und allgemeine Chemie | |
| dc.subject.other | selenium-nitrogen chains | |
| dc.subject.other | oxidation states | |
| dc.title | A Selenium-Nitrogen Chain with Selenium in Different Oxidation States | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201801121171 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2018-01-12T13:15:13Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 495-500 | |
| dc.relation.issn | 0044-2313 | |
| dc.relation.numberinseries | 7 | |
| dc.relation.volume | 643 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © Wiley-VCH-Verlag, 2017. This is a final draft version of an article whose final and definitive form has been published by Wiley-VCH-Verlag. Published in this repository with the kind permission of the publisher. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.relation.doi | 10.1002/zaac.201700031 | |
| dc.type.okm | A1 | |
