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dc.contributor.authorKarhu, Aino J.
dc.contributor.authorJämsä, Juho
dc.contributor.authorRautiainen, Mikko
dc.contributor.authorOilunkaniemi, Raija
dc.contributor.authorChivers, Tristram
dc.contributor.authorLaitinen, Risto S.
dc.date.accessioned2018-01-17T13:21:05Z
dc.date.available2018-03-16T22:45:12Z
dc.date.issued2017
dc.identifier.citationKarhu, A. J., Jämsä, J., Rautiainen, M., Oilunkaniemi, R., Chivers, T., & Laitinen, R. S. (2017). A Selenium-Nitrogen Chain with Selenium in Different Oxidation States. <em>Zeitschrift für anorganische und allgemeine Chemie</em>, 643 (7), 495-500. <a href="https://doi.org/10.1002/zaac.201700031">doi:10.1002/zaac.201700031</a>
dc.identifier.otherTUTKAID_73293
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/56771
dc.description.abstractThe reaction of tBuNH2 with a mixture of SeCl2 and SeOCl2 in a 6:2:1 molar ratio produces the novel selenium-nitrogen chain ClSeN(tBu)Se(O)Cl (4), in which the selenium atoms are in two different oxidation states, SeII and SeIV. The crystal structure of 4 is compared with that of the related SeII/SeII system ClSeN(tBu)SeCl (1) and differences are attributed to hyperconjugative effects. The energetics of the formation of 4 via two different routes are elucidated by PBE0/def2-TZVPP calculations.
dc.language.isoeng
dc.publisherWiley-VCH-Verlag
dc.relation.ispartofseriesZeitschrift für anorganische und allgemeine Chemie
dc.subject.otherselenium-nitrogen chains
dc.subject.otheroxidation states
dc.titleA Selenium-Nitrogen Chain with Selenium in Different Oxidation States
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201801121171
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-01-12T13:15:13Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange495-500
dc.relation.issn0044-2313
dc.relation.volume643
dc.type.versionacceptedVersion
dc.rights.copyright© Wiley-VCH-Verlag, 2017. This is a final draft version of an article whose final and definitive form has been published by Wiley-VCH-Verlag. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1002/zaac.201700031


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