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dc.contributor.authorRyazantsev, Sergey V.
dc.contributor.authorLundell, Jan
dc.contributor.authorFeldman, Vladimir I.
dc.contributor.authorKhriachtchev, Leonid
dc.date.accessioned2018-01-17T08:47:14Z
dc.date.available2018-12-05T22:35:47Z
dc.date.issued2018
dc.identifier.citationRyazantsev, S. V., Lundell, J., Feldman, V. I., & Khriachtchev, L. (2018). Photochemistry of the H2O/CO System Revisited : The HXeOH···CO Complex in a Xenon Matrix. <em>Journal of Physical Chemistry C</em>, 122 (1), 159-166. <a href="https://doi.org/10.1021/acs.jpca.7b10293">doi:10.1021/acs.jpca.7b10293</a>
dc.identifier.otherTUTKAID_75964
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/56764
dc.description.abstractWe report on the complex of a noble-gas hydride HXeOH with carbon monoxide. This species is prepared via the annealing-induced H + Xe + OH···CO reaction in a xenon matrix, the OH···CO complexes being produced by VUV photolysis of the H2O···CO complexes. The H–Xe stretching mode of the HXeOH···CO complex absorbs at 1590.3 cm–1 and it is blue-shifted by 12.7 cm–1 from the H–Xe stretching band of HXeOH monomer. The observed blue shift indicates the stabilization of the H–Xe bond upon complexation, which is characteristic of complexes of noble-gas hydrides. The HXeOH···CO species is the first complex of a noble-gas hydride with carbon monoxide and the second observed complex of HXeOH. On the basis of the MP2/aug-cc-pVTZ-PP calculations, the experimental complex is assigned to the structure, where the carbon atom of CO interacts with the oxygen atom of HXeOH.
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesJournal of Physical Chemistry C
dc.subject.otherphotochemistry
dc.subject.otherH2O/CO system
dc.subject.othercarbon monoxide
dc.subject.othergases
dc.subject.othermatrices
dc.titlePhotochemistry of the H2O/CO System Revisited : The HXeOH···CO Complex in a Xenon Matrix
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201801151205
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineKemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.identifier.doi10.1021/acs.jpca.7b10293
dc.date.updated2018-01-15T16:51:41Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange159-166
dc.relation.issn1932-7447
dc.relation.volume122
dc.type.versionacceptedVersion
dc.rights.copyright© 2017 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi


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