Fluorination of some highly functionalized cycloalkanes: chemoselectivity and substrate dependence
Remete, A. M., Nonn, M., Fustero, S., Haukka, M., Fülöp, F., & Kiss, L. (2017). Fluorination of some highly functionalized cycloalkanes: chemoselectivity and substrate dependence. Beilstein Journal of Organic Chemistry, 13, 2364-2371. https://doi.org/10.3762/bjoc.13.233
Published inBeilstein Journal of Organic Chemistry
© 2017 Remete et al.; licensee Beilstein-Institut. This is an open access article distributed under the terms of a Creative Commons License.
A study exploring the chemical behavior of some dihydroxylated β-amino ester stereo- and regioisomers, derived from unsaturated cyclic β-amino acids is described. The nucleophilic fluorinations involving hydroxy–fluorine exchange of some highly functionalized alicyclic diol derivatives have been carried out in view of selective fluorination, investigating substrate dependence, neighboring group assistance and chemodifferentiation.
Publication in research information system
MetadataShow full item record
Except where otherwise noted, this item's license is described as © 2017 Remete et al.; licensee Beilstein-Institut. This is an open access article distributed under the terms of a Creative Commons License.
Showing items with similar title or keywords.
Fluorine-containing functionalized cyclopentene scaffolds through ring contraction and deoxofluorination of various substituted cyclohexenes Remete, Attila Márió; Nonn, Melinda; Fustero, Santos; Haukka, Matti; Fülöp, Ferenc; Kiss, Lorand (Wiley-VCH, 2018)The fluorination of some highly‐functionalized cyclopentene derivatives, obtained from various substituted cyclohexenes through a ring‐opening/ring‐contraction procedure, has been investigated. The transformations were ...
Ouchakour, Lamiaa; Ábrahámi, Renáta A.; Forró, Enikő; Haukka, Matti; Fülöp, Ferenc; Kiss, Lorand (Wiley, 2019)An efficient synthetic approach for the construction of fluorine‐containing piperidine γ‐amino acid derivatives has been developed. The synthetic concept was based on oxidative ring opening of an unsaturated bicyclic ...
Rapid Self-Healing and Anion Selectivity in Metallosupramolecular Gels Assisted by Fluorine-Fluorine Interactions Arnedo Sánchez, Leticia; Nonappa; Bhowmik, Sandip; Hietala, Sami; Puttreddy, Rakesh; Lahtinen, Manu; De Cola, Luisa; Rissanen, Kari (Royal Society of Chemistry, 2017)Simple ML2 [M = Fe(II), Co(II), Ni(II)] complexes obtained from a perfluoroalkylamide derivative of 4-aminophenyl-2,2′,6,2′-terpyridine spontaneously, yet anion selectively, self-assemble into gels, which manifest an ...
Self-healing, luminescent metallogelation driven by synergistic metallophilic and fluorine–fluorine interactions Kolari, Kalle; Bulatov, Evgeny; Tatikonda, Rajendhraprasad; Bertula, Kia; Kalenius, Elina; Nonappa; Haukka, Matti (Royal Society of Chemistry, 2020)Square planar platinum(ii) complexes are attractive building blocks for multifunctional soft materials due to their unique optoelectronic properties. However, for soft materials derived from synthetically simple discrete ...
Remete, Attila Márió; Novák, Tamás T.; Nonn, Melinda; Haukka, Matti; Fülöp, Ferenc; Kiss, Loránd (Beilstein-Institut zur Förderung der Chemischen Wissenschaften, 2020)A study exploring halofluorination and fluoroselenation of some cyclic olefins, such as diesters, imides, and lactams with varied functionalization patterns and different structural architectures is described. The synthetic ...