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dc.contributor.authorGraham, Cameron M. E.
dc.contributor.authorValjus, Juuso
dc.contributor.authorPritchard, Taylor E.
dc.contributor.authorBoyle, Paul D.
dc.contributor.authorTuononen, Heikki
dc.contributor.authorRagogna, Paul J.
dc.date.accessioned2017-11-13T05:53:46Z
dc.date.available2018-10-14T21:35:40Z
dc.date.issued2017
dc.identifier.citationGraham, C. M. E., Valjus, J., Pritchard, T. E., Boyle, P. D., Tuononen, H., & Ragogna, P. J. (2017). Phosphorus-Chalcogen Ring Expansion and Metal Coordination. <em>Inorganic Chemistry</em>, 56 (21), 13500-13509. <a href="https://doi.org/10.1021/acs.inorgchem.7b02217">doi:10.1021/acs.inorgchem.7b02217</a>
dc.identifier.otherTUTKAID_75355
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/55840
dc.description.abstractThe reactivity of 4-membered (RPCh)2 rings (Ch = S, Se) that contain phosphorus in the +3 oxidation state is reported. These compounds undergo ring expansion to (RPCh)3 with the addition of a Lewis base. The 6-membered rings were found to be more stable than the 4-membered precursors, and the mechanism of their formation was investigated experimentally and by density functional theory calculations. The computational work identified two plausible mechanisms involving a phosphinidene chalcogenide intermediate, either as a free species or stabilized by a suitable base. Both the 4- and 6-membered rings were found to react with coinage metals, giving the same products: (RPCh)3 rings bound to the metal center from the phosphorus atom in tripodal fashion.
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesInorganic Chemistry
dc.subject.otherphosphorus-chalcogen
dc.subject.otherring expansion
dc.subject.othermetal coordination
dc.titlePhosphorus-Chalcogen Ring Expansion and Metal Coordination
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201711084165
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-11-08T10:15:11Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange13500-13509
dc.relation.issn0020-1669
dc.relation.volume56
dc.type.versionacceptedVersion
dc.rights.copyright© 2017 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccess
dc.relation.doi10.1021/acs.inorgchem.7b02217


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