dc.contributor.author | Tatikonda, Rajendhraprasad | |
dc.contributor.author | Bulatov, Evgeny | |
dc.contributor.author | Kalenius, Elina | |
dc.contributor.author | Haukka, Matti | |
dc.date.accessioned | 2017-11-10T09:41:30Z | |
dc.date.available | 2018-10-03T21:35:43Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Tatikonda, R., Bulatov, E., Kalenius, E., & Haukka, M. (2017). Construction of coordination polymers from semirigid ditopic 2,2´-Biimidazole derivatives : synthesis, crystal structures and characterization. <i>Crystal Growth and Design</i>, <i>17</i>(11), 5918-5926. <a href="https://doi.org/10.1021/acs.cgd.7b01034" target="_blank">https://doi.org/10.1021/acs.cgd.7b01034</a> | |
dc.identifier.other | CONVID_27265074 | |
dc.identifier.other | TUTKAID_75226 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/55820 | |
dc.description.abstract | Eight coordination polymers (CPs), {[Ag(L1)]ClO4}n (1), {[Ag(L2)1.5]ClO4·C2H3N}n (2a), {[Ag(L2)]ClO4}n (2b), [Zn(L1)Cl2]n (3), {[Zn(L2)Cl2]·CHCl3}n (4), {[Cu(L1)2Cl]Cl·H2O}n (5), [Cu2(L2)(μ-Cl)2]n (6), and [Cu4(L2)(μ-Cl)4]n (7) were synthesized via self-assembly of corresponding metal ions and biimidazole based ditopic ligands, 1,1′-bis(pyridin-3-ylmethyl)-2,2′-biimidazole L1 and 1,1′-bis(pyridin-4-ylmethyl)-2,2′-biimidazole L2. These ligands possess conformational flexibility and two pairs of coordination sites: pyridine nitrogen (NPy) atoms and imidazole nitrogen (NIm) atoms. Depending on the metal center in CPs, the biimidazole compounds act as tetra- (1, 7), tri- (2a), or bidentate (2a, 2b, 3-6) ligands binding to the metal either via NPy or NIm, or both. All these CPs were structurally fully characterized with single crystal X-ray structure, mass spectrometry, and NMR spectroscopy. The solid state photophysical properties and thermal stabilities of the CPs were also briefly studied in the solid state. | en |
dc.language.iso | eng | |
dc.publisher | American Chemical Society | |
dc.relation.ispartofseries | Crystal Growth and Design | |
dc.subject.other | coordination polymers | |
dc.title | Construction of coordination polymers from semirigid ditopic 2,2´-Biimidazole derivatives : synthesis, crystal structures and characterization | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201711014109 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Orgaaninen kemia | fi |
dc.contributor.oppiaine | Soveltava kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Organic Chemistry | en |
dc.contributor.oppiaine | Applied Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2017-11-01T13:15:16Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 5918-5926 | |
dc.relation.issn | 1528-7483 | |
dc.relation.numberinseries | 11 | |
dc.relation.volume | 17 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2017 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 278743 | |
dc.relation.grantnumber | 295581 | |
dc.relation.grantnumber | 284562 | |
dc.subject.yso | kemia | |
dc.subject.yso | polymeerit | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p1801 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p926 | |
dc.relation.doi | 10.1021/acs.cgd.7b01034 | |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
jyx.fundingprogram | Akatemiatutkija, SA | fi |
jyx.fundingprogram | Akatemiahanke, SA | fi |
jyx.fundingprogram | Akatemiatutkijan tutkimuskulut, SA | fi |
jyx.fundingprogram | Academy Research Fellow, AoF | en |
jyx.fundingprogram | Academy Project, AoF | en |
jyx.fundingprogram | Research costs of Academy Research Fellow, AoF | en |
jyx.fundinginformation | R.T., M.H., and E.K. kindly acknowledge the financial support from the Academy of Finland (Project Nos. 295581, 284562, and 278743). EU COST action CM 1302 “Smart Inorganic Polymers” is also gratefully acknowledged. | |
dc.type.okm | A1 | |