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dc.contributor.authorTatikonda, Rajendhraprasad
dc.contributor.authorBulatov, Evgeny
dc.contributor.authorKalenius, Elina
dc.contributor.authorHaukka, Matti
dc.date.accessioned2017-11-10T09:41:30Z
dc.date.available2018-10-03T21:35:43Z
dc.date.issued2017
dc.identifier.citationTatikonda, R., Bulatov, E., Kalenius, E., & Haukka, M. (2017). Construction of coordination polymers from semirigid ditopic 2,2´-Biimidazole derivatives : synthesis, crystal structures and characterization. <i>Crystal Growth and Design</i>, <i>17</i>(11), 5918-5926. <a href="https://doi.org/10.1021/acs.cgd.7b01034" target="_blank">https://doi.org/10.1021/acs.cgd.7b01034</a>
dc.identifier.otherCONVID_27265074
dc.identifier.otherTUTKAID_75226
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/55820
dc.description.abstractEight coordination polymers (CPs), {[Ag(L1)]ClO4}n (1), {[Ag(L2)1.5]ClO4·C2H3N}n (2a), {[Ag(L2)]ClO4}n (2b), [Zn(L1)Cl2]n (3), {[Zn(L2)Cl2]·CHCl3}n (4), {[Cu(L1)2Cl]Cl·H2O}n (5), [Cu2(L2)(μ-Cl)2]n (6), and [Cu4(L2)(μ-Cl)4]n (7) were synthesized via self-assembly of corresponding metal ions and biimidazole based ditopic ligands, 1,1′-bis(pyridin-3-ylmethyl)-2,2′-biimidazole L1 and 1,1′-bis(pyridin-4-ylmethyl)-2,2′-biimidazole L2. These ligands possess conformational flexibility and two pairs of coordination sites: pyridine nitrogen (NPy) atoms and imidazole nitrogen (NIm) atoms. Depending on the metal center in CPs, the biimidazole compounds act as tetra- (1, 7), tri- (2a), or bidentate (2a, 2b, 3-6) ligands binding to the metal either via NPy or NIm, or both. All these CPs were structurally fully characterized with single crystal X-ray structure, mass spectrometry, and NMR spectroscopy. The solid state photophysical properties and thermal stabilities of the CPs were also briefly studied in the solid state.en
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesCrystal Growth and Design
dc.subject.othercoordination polymers
dc.titleConstruction of coordination polymers from semirigid ditopic 2,2´-Biimidazole derivatives : synthesis, crystal structures and characterization
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201711014109
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineSoveltava kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineApplied Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-11-01T13:15:16Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange5918-5926
dc.relation.issn1528-7483
dc.relation.numberinseries11
dc.relation.volume17
dc.type.versionacceptedVersion
dc.rights.copyright© 2017 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber278743
dc.relation.grantnumber295581
dc.relation.grantnumber284562
dc.subject.ysokemia
dc.subject.ysopolymeerit
jyx.subject.urihttp://www.yso.fi/onto/yso/p1801
jyx.subject.urihttp://www.yso.fi/onto/yso/p926
dc.relation.doi10.1021/acs.cgd.7b01034
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramAkatemiatutkijan tehtävä, SAfi
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAkatemiatutkijan tutkimuskulut, SAfi
jyx.fundingprogramResearch post as Academy Research Fellow, AoFen
jyx.fundingprogramAcademy Project, AoFen
jyx.fundingprogramResearch costs of Academy Research Fellow, AoFen
jyx.fundinginformationR.T., M.H., and E.K. kindly acknowledge the financial support from the Academy of Finland (Project Nos. 295581, 284562, and 278743). EU COST action CM 1302 “Smart Inorganic Polymers” is also gratefully acknowledged.


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