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dc.contributor.authorGraham, Cameron M. E.
dc.contributor.authorPritchard, Taylor E.
dc.contributor.authorBoyle, Paul D.
dc.contributor.authorValjus, Juuso
dc.contributor.authorTuononen, Heikki
dc.contributor.authorRagogna, Paul J.
dc.date.accessioned2017-08-09T09:19:04Z
dc.date.available2018-01-10T22:45:10Z
dc.date.issued2017
dc.identifier.citationGraham, C. M. E., Pritchard, T. E., Boyle, P. D., Valjus, J., Tuononen, H., & Ragogna, P. J. (2017). Trapping Rare and Elusive Phosphinidene Chalcogenides. <em>Angewandte Chemie International Edition</em>, 56 (1), 6236-6240. <a href="https://doi.org/10.1002/anie.201611196">doi:10.1002/anie.201611196</a>
dc.identifier.otherTUTKAID_72519
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/55049
dc.description.abstractFour-membered rings with a P2Ch2 core (Ch=S, Se) and phosphorus in the +3 oxidation state have been synthesized. The utility of these rings as a source of monomeric phosphinidene chalcogenides was probed by the addition of an N-heterocyclic carbene, resulting in a base-stabilized phosphinidene sulfide. Similarly, persistence of the phosphinidene selenide in solution was shown through cycloaddition chemistry with 2,3-dimethylbutadiene at elevated temperatures. The observed reactivity was explained by detailed computational work that established the conditions upon which the P2Ch2 rings can liberate phosphinidene chalcogenides.
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.ispartofseriesAngewandte Chemie International Edition
dc.subject.otherphosphinidenes
dc.titleTrapping Rare and Elusive Phosphinidene Chalcogenides
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201707213345
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-07-21T06:40:33Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange6236-6240
dc.relation.issn1433-7851
dc.relation.volume56
dc.type.versionacceptedVersion
dc.rights.copyright© 2017 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1002/anie.201611196


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