dc.contributor.author | Graham, Cameron M. E. | |
dc.contributor.author | Pritchard, Taylor E. | |
dc.contributor.author | Boyle, Paul D. | |
dc.contributor.author | Valjus, Juuso | |
dc.contributor.author | Tuononen, Heikki | |
dc.contributor.author | Ragogna, Paul J. | |
dc.date.accessioned | 2017-08-09T09:19:04Z | |
dc.date.available | 2018-01-10T22:45:10Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Graham, C. M. E., Pritchard, T. E., Boyle, P. D., Valjus, J., Tuononen, H., & Ragogna, P. J. (2017). Trapping Rare and Elusive Phosphinidene Chalcogenides. <i>Angewandte Chemie International Edition</i>, <i>56</i>(1), 6236-6240. <a href="https://doi.org/10.1002/anie.201611196" target="_blank">https://doi.org/10.1002/anie.201611196</a> | |
dc.identifier.other | CONVID_26462088 | |
dc.identifier.other | TUTKAID_72519 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/55049 | |
dc.description.abstract | Four-membered rings with a P2Ch2 core (Ch=S, Se) and phosphorus in the +3 oxidation state have been synthesized. The utility of these rings as a source of monomeric phosphinidene chalcogenides was probed by the addition of an N-heterocyclic carbene, resulting in a base-stabilized phosphinidene sulfide. Similarly, persistence of the phosphinidene selenide in solution was shown through cycloaddition chemistry with 2,3-dimethylbutadiene at elevated temperatures. The observed reactivity was explained by detailed computational work that established the conditions upon which the P2Ch2 rings can liberate phosphinidene chalcogenides. | |
dc.language.iso | eng | |
dc.publisher | Wiley-VCH | |
dc.relation.ispartofseries | Angewandte Chemie International Edition | |
dc.subject.other | phosphinidenes | |
dc.title | Trapping Rare and Elusive Phosphinidene Chalcogenides | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201707213345 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Fysikaalinen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Physical Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2017-07-21T06:40:33Z | |
dc.type.coar | journal article | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 6236-6240 | |
dc.relation.issn | 1433-7851 | |
dc.relation.numberinseries | 1 | |
dc.relation.volume | 56 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2017 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.doi | 10.1002/anie.201611196 | |