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dc.contributor.authorElantabli, Fatma M.
dc.contributor.authorRadebe, Mduduzi P.
dc.contributor.authorMotswainyana, William M.
dc.contributor.authorOwaga, Bernard O.
dc.contributor.authorEl-Medani, Samir M.
dc.contributor.authorEkengard, Erik
dc.contributor.authorHaukka, Matti
dc.contributor.authorNordlander, Ebbe
dc.contributor.authorOnani, Martin O.
dc.date.accessioned2017-06-02T06:24:50Z
dc.date.available2019-04-22T21:35:21Z
dc.date.issued2017
dc.identifier.citationElantabli, F. M., Radebe, M. P., Motswainyana, W. M., Owaga, B. O., El-Medani, S. M., Ekengard, E., Haukka, M., Nordlander, E., & Onani, M. O. (2017). Thiophene based imino-pyridyl palladium(II) complexes : Synthesis, molecular structures and Heck coupling reactions. <i>Journal of Organometallic Chemistry</i>, <i>843</i>, 40-47. <a href="https://doi.org/10.1016/j.jorganchem.2017.04.022" target="_blank">https://doi.org/10.1016/j.jorganchem.2017.04.022</a>
dc.identifier.otherCONVID_26963580
dc.identifier.otherTUTKAID_73567
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/54262
dc.description.abstractThe new compounds (5-methyl-2-thiophene-2-pyridyl(R))imine [R = methyl (L1); R = ethyl (L2)] and (5-bromo-2-thiophene-2-pyridyl(R)imine [R = methyl (L3); R = ethyl (L4)] were successfully synthesized via Schiff base condensation reaction and obtained in good yields. These potential ligands were reacted with [PdCl2(COD)] and [PdClMe(COD)] to give the corresponding complexes [PdCl2(L)] (L = L1-L4; 1–4) and [PdClMe(L)] (L = L1-L4; 5–8). All compounds were characterized by IR, 1H and 13C NMR spectroscopy, elemental analysis and mass spectrometry. The molecular structures of 1, 2, 6 and 8 were confirmed by X-ray crystallography. The complexes were evaluated as catalyst precursors for standard Heck coupling reactions and showed significant catalytic activities that could be correlated with steric and electronic influences.
dc.language.isoeng
dc.publisherElsevier
dc.relation.ispartofseriesJournal of Organometallic Chemistry
dc.subject.otherimino-pyridyl
dc.subject.othermolecular structures
dc.subject.otherheck reactions
dc.titleThiophene based imino-pyridyl palladium(II) complexes : Synthesis, molecular structures and Heck coupling reactions
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201706012624
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-06-01T12:15:11Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange40-47
dc.relation.issn0022-328X
dc.relation.numberinseries0
dc.relation.volume843
dc.type.versionacceptedVersion
dc.rights.copyright© 2017 Elsevier B.V. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.subject.ysopalladium
dc.subject.ysosynteesi
jyx.subject.urihttp://www.yso.fi/onto/yso/p26929
jyx.subject.urihttp://www.yso.fi/onto/yso/p8467
dc.relation.doi10.1016/j.jorganchem.2017.04.022


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