| dc.contributor.author | Elantabli, Fatma M. | |
| dc.contributor.author | Radebe, Mduduzi P. | |
| dc.contributor.author | Motswainyana, William M. | |
| dc.contributor.author | Owaga, Bernard O. | |
| dc.contributor.author | El-Medani, Samir M. | |
| dc.contributor.author | Ekengard, Erik | |
| dc.contributor.author | Haukka, Matti | |
| dc.contributor.author | Nordlander, Ebbe | |
| dc.contributor.author | Onani, Martin O. | |
| dc.date.accessioned | 2017-06-02T06:24:50Z | |
| dc.date.available | 2019-04-22T21:35:21Z | |
| dc.date.issued | 2017 | |
| dc.identifier.citation | Elantabli, F. M., Radebe, M. P., Motswainyana, W. M., Owaga, B. O., El-Medani, S. M., Ekengard, E., Haukka, M., Nordlander, E., & Onani, M. O. (2017). Thiophene based imino-pyridyl palladium(II) complexes : Synthesis, molecular structures and Heck coupling reactions. <i>Journal of Organometallic Chemistry</i>, <i>843</i>, 40-47. <a href="https://doi.org/10.1016/j.jorganchem.2017.04.022" target="_blank">https://doi.org/10.1016/j.jorganchem.2017.04.022</a> | |
| dc.identifier.other | CONVID_26963580 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/54262 | |
| dc.description.abstract | The new compounds (5-methyl-2-thiophene-2-pyridyl(R))imine [R = methyl (L1); R = ethyl (L2)] and (5-bromo-2-thiophene-2-pyridyl(R)imine [R = methyl (L3); R = ethyl (L4)] were successfully synthesized via Schiff base condensation reaction and obtained in good yields. These potential ligands were reacted with [PdCl2(COD)] and [PdClMe(COD)] to give the corresponding complexes [PdCl2(L)] (L = L1-L4; 1–4) and [PdClMe(L)] (L = L1-L4; 5–8). All compounds were characterized by IR, 1H and 13C NMR spectroscopy, elemental analysis and mass spectrometry. The molecular structures of 1, 2, 6 and 8 were confirmed by X-ray crystallography. The complexes were evaluated as catalyst precursors for standard Heck coupling reactions and showed significant catalytic activities that could be correlated with steric and electronic influences. | |
| dc.language.iso | eng | |
| dc.publisher | Elsevier | |
| dc.relation.ispartofseries | Journal of Organometallic Chemistry | |
| dc.subject.other | imino-pyridyl | |
| dc.subject.other | molecular structures | |
| dc.subject.other | heck reactions | |
| dc.title | Thiophene based imino-pyridyl palladium(II) complexes : Synthesis, molecular structures and Heck coupling reactions | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201706012624 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2017-06-01T12:15:11Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 40-47 | |
| dc.relation.issn | 0022-328X | |
| dc.relation.numberinseries | 0 | |
| dc.relation.volume | 843 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © 2017 Elsevier B.V. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.type.publication | article | |
| dc.subject.yso | palladium | |
| dc.subject.yso | synteesi | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p26929 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p8467 | |
| dc.relation.doi | 10.1016/j.jorganchem.2017.04.022 | |
| dc.type.okm | A1 | |
