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dc.contributor.authorChen, Yan-Cong
dc.contributor.authorLiu, Jun-Liang
dc.contributor.authorLan, Yanhua
dc.contributor.authorZhong, Zhi-Qiang
dc.contributor.authorMansikkamäki, Akseli
dc.contributor.authorUngur, Liviu
dc.contributor.authorLi, Quan-Wen
dc.contributor.authorJia, Jian-Hua
dc.contributor.authorChibotaru, Liviu F.
dc.contributor.authorHan, Jun-Bo
dc.contributor.authorWernsdorfer, Wolfgang
dc.contributor.authorChen, Xiao-Ming
dc.contributor.authorTong, Ming-Liang
dc.date.accessioned2017-05-08T07:18:24Z
dc.date.available2018-02-20T22:45:11Z
dc.date.issued2017
dc.identifier.citationChen, Y.-C., Liu, J.-L., Lan, Y., Zhong, Z.-Q., Mansikkamäki, A., Ungur, L., . . . Tong, M.-L. (2017). Dynamic Magnetic and Optical Insight into a High Performance Pentagonal Bipyramidal Dy(III) Single-Ion Magnet. <em>Chemistry: A European Journal</em>, 23 (24), 5708-5715. <a href="https://doi.org/10.1002/chem.201606029">doi:10.1002/chem.201606029</a>
dc.identifier.otherTUTKAID_72887
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/53813
dc.description.abstractThe pentagonal bipyramidal single-ion magnets (SIMs) are among the most attractive prototypes of high-performance single-molecule magnets (SMMs). Here, a fluorescence-active phosphine oxide ligand CyPh2PO (=cyclohexyl(diphenyl)phosphine oxide) was introduced into [Dy(CyPh2PO)2(H2O)5]Br3⋅2 (CyPh2PO)⋅EtOH⋅3 H2O, and combined dynamic magnetic measurement, optical characterization, ab initio calculation, and magneto-optical correlation of this high-performance pseudo-D5h DyIII SIM with large Ueff (508(2) K) and high magnetic hysteresis temperature (19 K) were performed. This work provides a deeper insight into the rational design of promising molecular magnets.
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.ispartofseriesChemistry: A European Journal
dc.subject.otherdynamic magnetic measurements
dc.subject.othersingle-molecule magnets
dc.subject.othermolecular magnets
dc.titleDynamic Magnetic and Optical Insight into a High Performance Pentagonal Bipyramidal Dy(III) Single-Ion Magnet
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201705032159
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-05-03T06:15:14Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange5708-5715
dc.relation.issn0947-6539
dc.relation.volume23
dc.type.versionacceptedVersion
dc.rights.copyright© 2017 Wiley-VCH Verlag GmbH &Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1002/chem.201606029


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