Näytä suppeat kuvailutiedot

dc.contributor.authorPuttreddy, Rakesh
dc.contributor.authorBeyeh, Ngong Kodiah
dc.contributor.authorRissanen, Kari
dc.date.accessioned2016-07-01T05:47:44Z
dc.date.available2016-07-01T05:47:44Z
dc.date.issued2016
dc.identifier.citationPuttreddy, R., Beyeh, N. K., & Rissanen, K. (2016). Inclusion complexes of Cethyl-2-methylresorcinarene and pyridine N-oxides: breaking the C–I⋯−O–N+ halogen bond by host–guest complexation. <i>CrystEngComm</i>, <i>18</i>(5), 793-799. <a href="https://doi.org/10.1039/C5CE02354H" target="_blank">https://doi.org/10.1039/C5CE02354H</a>
dc.identifier.otherCONVID_25492095
dc.identifier.otherTUTKAID_68876
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/50665
dc.description.abstractC ethyl-2-Methylresorcinarene forms host–guest complexes with aromatic N-oxides through multiple intra- and intermolecular hydrogen bonds and C–H⋯π interactions. The host shows conformational flexibility to accommodate 3-methylpyridine N-oxide, while retaining a crown conformation for 2-methyl- and 4-methoxypyridine N-oxides highlighting the substituent effect of the guest. N-Methylmorpholine N-oxide, a 6-membered ring aliphatic N-oxide with a methyl at the N-oxide nitrogen, is bound by the equatorial −N–CH3 group located deep in the cavity. 2-Iodopyridine N-oxide is the only guest that manifests intermolecular N–O⋯I–C halogen bond interactions, which are broken down by the host resulting in a 2 : 2 pseudocapsular complex stabilized by additional C–I⋯π interactions between the two 2-iodopyridine N-oxides located in two adjacent hosts. These host–guest complexes were analyzed in the solid state by single crystal X-ray crystallography and in solution by 1H NMR spectroscopy.en
dc.languageeng
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofseriesCrystEngComm
dc.subject.otherhalogeenisidos
dc.subject.otherhost–guest complexation
dc.subject.otherhalogen bond
dc.subject.otherCethyl-2-methylresorcinarene
dc.subject.otherpyridine N-oxides
dc.titleInclusion complexes of Cethyl-2-methylresorcinarene and pyridine N-oxides: breaking the C–I⋯−O–N+ halogen bond by host–guest complexation
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201606303410
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2016-06-30T12:15:13Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange793-799
dc.relation.issn1466-8033
dc.relation.numberinseries5
dc.relation.volume18
dc.type.versionpublishedVersion
dc.rights.copyright© the Authors, 2016. The journal is © The Royal Society of Chemistry 2016. This is an open access article distributed under a Creative Commons Attribution 3.0 Unported Licence.
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber263256
dc.subject.ysokemialliset sidokset
dc.subject.ysosupramolekulaarinen kemia
jyx.subject.urihttp://www.yso.fi/onto/yso/p10130
jyx.subject.urihttp://www.yso.fi/onto/yso/p37759
dc.rights.urlhttps://creativecommons.org/licenses/by/3.0/
dc.relation.doi10.1039/C5CE02354H
dc.relation.funderSuomen Akatemiafi
dc.relation.funderResearch Council of Finlanden
jyx.fundingprogramAkatemiaprofessorin tehtävä, SAfi
jyx.fundingprogramResearch post as Academy Professor, AoFen
jyx.fundinginformationThe Academy of Finland (K. R.: grant no. 265328 and 263256; N. K. B.: grant no. 258653), the University of Jyvaskyla and Aalto University are gratefully acknowledged for financial support.
dc.type.okmA1


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Näytä suppeat kuvailutiedot

© the Authors, 2016. The journal is © The Royal Society of Chemistry 2016. This is an open access article distributed under a Creative Commons Attribution 3.0 Unported Licence.
Ellei muuten mainita, aineiston lisenssi on © the Authors, 2016. The journal is © The Royal Society of Chemistry 2016. This is an open access article distributed under a Creative Commons Attribution 3.0 Unported Licence.