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dc.contributor.authorBhattacharyya, Anik
dc.contributor.authorGhosh, Biswa Nath
dc.contributor.authorRissanen, Kari
dc.contributor.authorChattopadhyay, Shouvik
dc.date.accessioned2016-06-30T09:50:26Z
dc.date.available2018-04-22T21:45:10Z
dc.date.issued2016
dc.identifier.citationBhattacharyya, A., Ghosh, B. N., Rissanen, K., & Chattopadhyay, S. (2016). Synthesis, characterization and self-assembly of three dicyanamide bridged polynuclear copper(II) complexes with N2O donor tridentate Schiff bases as blocking ligands. <em>Polyhedron</em>, 117 (15 October), 138-147. <a href="http://dx.doi.org/10.1016/j.poly.2016.04.037">doi:10.1016/j.poly.2016.04.037</a>
dc.identifier.otherTUTKAID_69901
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/50654
dc.description.abstractThree copper(II) complexes [Cu(L1)(μ1,5-dca)]n (1), [Cu(L2)(μ1,5-dca)]n (2) and [Cu(L3)(μ1,5-dca)]n (3) [where HL1 = (1-(2-(dimethylamino)ethylimino)ethyl) naphthalene-1-ol, HL2 = (1-(2-(methylamino)ethylimino)ethyl) naphthalene-1-ol and HL3 = (1-(2-(ethylamino)ethylimino)ethyl)naphthalene-1-ol] have been synthesized and characterized by elemental analysis, IR and UV–Vis spectroscopy. The structure of each complex has been confirmed by single-crystal X-ray diffraction studies. In all three complexes, copper(II) centres are bridged by dicyanamide in end to end fashion. Complexes 1 and 2 are zigzag polymers, whereas complex 3 is a helical one. The weak forces like C–H⋯π and π⋯π interactions influence the self-assembly process in all three complexes. Such types of interactions lead to the formation of interesting supra molecular networks in three complexes.
dc.language.isoeng
dc.publisherPergamon
dc.relation.ispartofseriesPolyhedron
dc.subject.othercopper(II)
dc.subject.otherpolynuclear
dc.subject.otherschiff base
dc.subject.otherdicyanamide
dc.subject.othercrystal structure
dc.titleSynthesis, characterization and self-assembly of three dicyanamide bridged polynuclear copper(II) complexes with N2O donor tridentate Schiff bases as blocking ligands
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201606303401
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2016-06-30T09:15:09Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange138-147
dc.relation.issn0277-5387
dc.relation.volume117
dc.type.versionacceptedVersion
dc.rights.copyright© 2016 Elsevier Ltd. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1016/j.poly.2016.04.037


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