Show simple item record

dc.contributor.authorSillanpää, Reijo
dc.contributor.authorHänninen, Mikko M.
dc.date.accessioned2016-02-03T11:39:45Z
dc.date.available2016-02-03T11:39:45Z
dc.date.issued2013
dc.identifier.citationSillanpää, R., & Hänninen, M. M. (2013). A cocrystal of two Mo(VI) complexes bearing different diastereomers of the 2,4-di-tert-butyl-6-{[(1-oxido-1-phenylpropan-2-yl)(methyl)amino]methyl}phenolate ligand derived from (+)-ephedrine. <em>Acta Crystallographica Section C</em>, 69 (Pt 5), 509-512. <a href="http://dx.doi.org/10.1107/S0108270113010652">doi:10.1107/S0108270113010652</a>
dc.identifier.otherTUTKAID_59336
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/48599
dc.description.abstractThe title cocrystal contains two chiral conformational diastereomers, viz. (1S,2R,RN)- and (1S,2R,SN)-, of [2,4-ditert-butyl-6-{[(1-oxido-1-phenylpropan-2-yl)(methyl)amino]- methyl}phenolato](methanol)-cis-dioxidomolybdenum(VI), [Mo(C25H35NO2)O2(CH3OH)], representing the first example of a structurally characterized molybdenum complex with enantiomerically pure ephedrine derivative ligands. The MoVI cations exhibit differently distorted octahedral coordination environments, with two oxide ligands positioned cis to each other. The remainder of the coordination comprises phenoxide, alkoxide and methanol O atoms, with an amine N atom completing the octahedron. The distinct complexes are linked by strong intermolecular O—HO hydrogen bonds, resulting in one-dimensional molecular chains. Furthermore, the phenyl rings are involved in weak T-shaped/edge-to-face – interactions with each other.
dc.language.isoeng
dc.publisherWiley-Blackwell
dc.relation.ispartofseriesActa Crystallographica Section C
dc.subject.othercocrystal
dc.subject.othermolybdenum complexes
dc.subject.otherephedrine derivative ligands
dc.titleA cocrystal of two Mo(VI) complexes bearing different diastereomers of the 2,4-di-tert-butyl-6-{[(1-oxido-1-phenylpropan-2-yl)(methyl)amino]methyl}phenolate ligand derived from (+)-ephedrine
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201602031421
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2016-02-03T10:15:35Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange509-512
dc.relation.issn0108-2701
dc.relation.volume69
dc.type.versionpublishedVersion
dc.rights.copyright© 2013 International Union of Crystallography. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1107/S0108270113010652


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record