Poly[[myy-N,N'-bis(2-hydroxyethyl)-N,N,N',N'-tetramethylpropane-1,3-diaminium-kappa2O:O']tetra-myy-bromido-dibromidodimanganese(II)]
Rinta, H., Peuronen, A., & Lahtinen, M. (2012). Poly[[myy-N,N'-bis(2-hydroxyethyl)-N,N,N',N'-tetramethylpropane-1,3-diaminium-kappa2O:O']tetra-myy-bromido-dibromidodimanganese(II)]. Acta Crystallographica E, E68(12), m1453-m1454. https://doi.org/10.1107/S1600536812044765
Published in
Acta Crystallographica EDate
2012Copyright
© the Authors, 2012. This is an open access article publised by ICUr.
The asymmetric unit of the title three-dimensional coordination
polymer, [Mn2Br6(C11H28N2O2)]n, consists of one MnII
cation, half of a dicationic N,N0
-bis(2-hydroxyethyl)-
N,N,N0
,N0
-tetramethylpropane-1,3-diaminium ligand (L)
(the other half being generated by a twofold rotation axis),
and three bromide ions. The MnII cation is coordinated by a
single L ligand via the hydroxy O atom and by five bromide
ions, resulting in a distorted octahedral MnBr5O coordination
geometry. Four of the bromide ions are bridging to two
adjacent MnII atoms, thereby forming polymeric chains along
the a and b axes. The L units act as links between
neighbouring Mn—(-Br)2—Mn chains, also forming a
polymeric continuum along the c axis, which completes the
formation of a three-dimensional network. Classical O—
HBr hydrogen bonds are present. The distance between
adjacent MnII atoms is 4.022 (1) A˚ .
Publisher
IuCrISSN Search the Publication Forum
1600-5368Keywords
Original source
http://journals.iucr.org/e/issues/2012/12/00/fj2604/index.htmlPublication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/21707080
Metadata
Show full item recordCollections
Related items
Showing items with similar title or keywords.
-
3,4-Dimethoxy-4'-methylbiphenyl
Lahtinen, Manu; Nummelin, Sami (International Union of Crystallography, 2013)In the title compound, C15H16O2, the dihedral angle between the planes of the aromatic rings is 30.5 (2). In the crystal, molecules are linked via C—HO hydrogen bonds and C— H interactions, forming a two-dimensional ... -
Methyl 3',5'-dimethoxybiphenyl-4-carboxylate
Lahtinen, Manu; Nättinen, Kalle; Nummelin, Sami (International Union of Crystallography, 2013)In the title compound, C16H16O4, the dihedral angle between the benzene rings is 28.9 (2). In the crystal, molecules are packed in layers parallel to the b axis in which they are connected via weak intermolecular C—HO ... -
Methyl 3',4',5'-trimethoxybiphenyl-4-carboxylate
Lahtinen, Manu; Nättinen, Kalle; Nummelin, Sami (International Union of Crystallography, 2013)In the title compound, C17H18O5, the dihedral angle between the benzene rings is 31.23 (16). In the crystal, the molecules are packed in an antiparallel fashion in layers along the a axis. In each layer, very weak C—HO ... -
3,4,5-Trimethoxy-4'-methylbiphenyl
Lahtinen, Manu; Nättinen, Kalle; Nummelin, Sami (International Union of Crystallography, 2013)In the title compound, C16H18O3, the dihedral angle between the benzene rings is 33.4 (2)°. In the crystal, molecules are packed in a zigzag arrangement along the b-axis and are interconnected via weak C-H...O hydrogen ... -
3,5-Dimethoxy-4'-methylbiphenyl
Lahtinen, Manu; Nättinen, Kalle; Nummelin, Sami (International Union of Crystallography, 2013)The title compound, C15H16O2, crystallizes with three independent molecules in the asymmetric unit. The intramolecular torsion angle between the aromatic rings of each molecule are 36.4 (3), 41.3 (3) and 37.8 (3). In ...