dc.contributor.author | Lips, Felicitas | |
dc.contributor.author | Fettinger, James C. | |
dc.contributor.author | Mansikkamäki, Akseli | |
dc.contributor.author | Tuononen, Heikki | |
dc.contributor.author | Power, Philip | |
dc.date.accessioned | 2015-12-01T07:35:01Z | |
dc.date.available | 2015-12-01T07:35:01Z | |
dc.date.issued | 2014 | |
dc.identifier.citation | Lips, F., Fettinger, J. C., Mansikkamäki, A., Tuononen, H., & Power, P. (2014). Reversible Complexation of Ethylene by a Silylene under Ambient Conditions. <i>Journal of the American Chemical Society</i>, <i>136</i>(2), 634-637. <a href="https://doi.org/10.1021/ja411951y" target="_blank">https://doi.org/10.1021/ja411951y</a> | |
dc.identifier.other | CONVID_23610284 | |
dc.identifier.other | TUTKAID_61440 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/47897 | |
dc.description.abstract | Treatment of toluene solutions of the silylenes Si(SArMe6)2 (ArMe6 = C6H3-2,6(C6H2-2,4,6-Me3)2, 1) or Si(SArPri4)2 (ArPri4 = C6H3-2,6(C6H3-2,6-Pri2)2, 2) with excess ethylene gas affords the siliranes (ArMe6S)2tiebar above startSiCH2tiebar above endCH2 (3) or (ArPri4S)2tiebar above startSiCH2tiebar above endCH2 (4). Silirane 4 evolves ethylene spontaneously at room temperature in toluene solution. A Van’t Hoff analysis by variable-temperature 1H NMR spectroscopy showed that ΔGassn = −24.9(2.5) kJ mol–1 for 4. A computational study of the reaction mechanism using a model silylene Si(SPh)2 (Ph = C6H5) was in harmony with the Van’t Hoff analysis, yielding ΔGassn = −24 kJ mol–1 and an activation energy ΔG⧧ = 54 kJ mol–1. | |
dc.language.iso | eng | |
dc.publisher | American Chemical Society | |
dc.relation.ispartofseries | Journal of the American Chemical Society | |
dc.subject.other | metallyleeni-isosyanidi -kompleksit | |
dc.subject.other | metallylene-isocyanide complexes | |
dc.subject.other | bonding analysis | |
dc.title | Reversible Complexation of Ethylene by a Silylene under Ambient Conditions | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201511263835 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Fysikaalinen kemia | fi |
dc.contributor.oppiaine | Physical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2015-11-26T07:15:05Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 634-637 | |
dc.relation.issn | 0002-7863 | |
dc.relation.numberinseries | 2 | |
dc.relation.volume | 136 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2013 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.subject.yso | sitoutuminen (toiminta) | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p13419 | |
dc.relation.doi | 10.1021/ja411951y | |
dc.type.okm | A1 | |