Show simple item record

dc.contributor.authorMorgan, Ian
dc.contributor.authorPeuronen, Anssi
dc.contributor.authorHänninen, Mikko M.
dc.contributor.authorReed, Robert
dc.contributor.authorClerac, Rodolphe
dc.contributor.authorTuononen, Heikki
dc.date.accessioned2015-11-30T10:07:51Z
dc.date.available2015-11-30T10:07:51Z
dc.date.issued2014
dc.identifier.citationMorgan, I., Peuronen, A., Hänninen, M. M., Reed, R., Clerac, R., & Tuononen, H. (2014). 1-Phenyl-3-(pyrid-2-yl)benzo[e][1,2,4]triazinyl: The First “Blatter Radical” for Coordination Chemistry. <i>Inorganic Chemistry</i>, <i>53</i>(1), 33-35. <a href="https://doi.org/10.1021/ic402954p" target="_blank">https://doi.org/10.1021/ic402954p</a>
dc.identifier.otherCONVID_23053521
dc.identifier.otherTUTKAID_59510
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/47865
dc.description.abstractA neutral air- and moisture-stable N,N′-chelating radical ligand, 1-phenyl-3-(pyrid-2-yl)benzo[e][1,2,4]triazinyl (1) was synthesized and characterized by electron paramagnetic resonance spectroscopy, X-ray crystallography, and magnetic measurements. Subsequent reaction of 1 with Cu(hfac)2·2H2O (hfac = hexafluoroacetylacetonate) under ambient conditions afforded the coordination complex Cu(1)(hfac)2 in which the radical binds to the metal in a bidentate fashion. Magnetic susceptibility data collected from 1.8 to 300 K indicate a strong ferromagnetic metal-radical interaction in the complex and weak antiferromagnetic radical···radical interactions between the Cu(1)(hfac)2 units. Detailed computational investigations support this assignment. Radical 1 is a new addition to the growing library of 1,2,4-triazinyl radicals and the first member of this family of paramagnetic species synthesized specifically for coordination purposes.
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesInorganic Chemistry
dc.subject.otherBlatter radikaali
dc.subject.otherpysyvät radikaalit
dc.subject.othermetallikompleksit
dc.subject.otherBlatter radical
dc.subject.otherstable radicals
dc.subject.othermetal complexes
dc.title1-Phenyl-3-(pyrid-2-yl)benzo[e][1,2,4]triazinyl: The First “Blatter Radical” for Coordination Chemistry
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201511253826
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2015-11-25T13:16:06Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange33-35
dc.relation.issn0020-1669
dc.relation.numberinseries1
dc.relation.volume53
dc.type.versionacceptedVersion
dc.rights.copyright© 2013 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1021/ic402954p


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record