dc.contributor.author | Morgan, Ian | |
dc.contributor.author | Peuronen, Anssi | |
dc.contributor.author | Hänninen, Mikko M. | |
dc.contributor.author | Reed, Robert | |
dc.contributor.author | Clerac, Rodolphe | |
dc.contributor.author | Tuononen, Heikki | |
dc.date.accessioned | 2015-11-30T10:07:51Z | |
dc.date.available | 2015-11-30T10:07:51Z | |
dc.date.issued | 2014 | |
dc.identifier.citation | Morgan, I., Peuronen, A., Hänninen, M. M., Reed, R., Clerac, R., & Tuononen, H. (2014). 1-Phenyl-3-(pyrid-2-yl)benzo[e][1,2,4]triazinyl: The First “Blatter Radical” for Coordination Chemistry. <i>Inorganic Chemistry</i>, <i>53</i>(1), 33-35. <a href="https://doi.org/10.1021/ic402954p" target="_blank">https://doi.org/10.1021/ic402954p</a> | |
dc.identifier.other | CONVID_23053521 | |
dc.identifier.other | TUTKAID_59510 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/47865 | |
dc.description.abstract | A neutral air- and moisture-stable N,N′-chelating radical ligand, 1-phenyl-3-(pyrid-2-yl)benzo[e][1,2,4]triazinyl (1) was synthesized and characterized by electron paramagnetic resonance spectroscopy, X-ray crystallography, and magnetic measurements. Subsequent reaction of 1 with Cu(hfac)2·2H2O (hfac = hexafluoroacetylacetonate) under ambient conditions afforded the coordination complex Cu(1)(hfac)2 in which the radical binds to the metal in a bidentate fashion. Magnetic susceptibility data collected from 1.8 to 300 K indicate a strong ferromagnetic metal-radical interaction in the complex and weak antiferromagnetic radical···radical interactions between the Cu(1)(hfac)2 units. Detailed computational investigations support this assignment. Radical 1 is a new addition to the growing library of 1,2,4-triazinyl radicals and the first member of this family of paramagnetic species synthesized specifically for coordination purposes. | |
dc.language.iso | eng | |
dc.publisher | American Chemical Society | |
dc.relation.ispartofseries | Inorganic Chemistry | |
dc.subject.other | Blatter radikaali | |
dc.subject.other | pysyvät radikaalit | |
dc.subject.other | metallikompleksit | |
dc.subject.other | Blatter radical | |
dc.subject.other | stable radicals | |
dc.subject.other | metal complexes | |
dc.title | 1-Phenyl-3-(pyrid-2-yl)benzo[e][1,2,4]triazinyl: The First “Blatter Radical” for Coordination Chemistry | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201511253826 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2015-11-25T13:16:06Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 33-35 | |
dc.relation.issn | 0020-1669 | |
dc.relation.numberinseries | 1 | |
dc.relation.volume | 53 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2013 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.doi | 10.1021/ic402954p | |
dc.type.okm | A1 | |