Comment on "Crystallographic Snapshot of an Arrested Intermediate in the Biomimetic Activation of CO2"
Hurmalainen, J., Land, M. A., Robertson, K. N., Roberts, C., Morgan, I., Tuononen, H., & Clyburne, J. A. C. (2015). Comment on "Crystallographic Snapshot of an Arrested Intermediate in the Biomimetic Activation of CO2". Angewandte Chemie International Edition, 54(26), 7484-7487. https://doi.org/10.1002/anie.201411654
Published inAngewandte Chemie International Edition
DisciplineEpäorgaaninen ja analyyttinen kemiaNanoscience CenterInorganic and Analytical ChemistryNanoscience Center
© 2015 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
Out of focus: A recent Communication published in this journal describes the synthesis of [nBu4N]HCO3. The authors performed a single-crystal X-ray study that revealed a putative species described as an incipient hydroxide ion engaging in a long, and presumably weak, interaction with CO2. Our recent exploration of the coordination chemistry of CO2 with small ions leads us to believe that such an exceptional bonding situation is unlikely. Instead, we argue that the crystal structure is that of [nBu4N]O2CCH3 and therefore not representative of the bulk powder from the synthesis.
PublisherWiley - VCH Verlag GmbH & Co. KGaA
ISSN Search the Publication Forum1433-7851
Publication in research information system
MetadataShow full item record
Showing items with similar title or keywords.
Experimental and computational studies of unconventional main group compounds : stable radicals and reactive intermediates Hurmalainen, Juha (University of Jyväskylä, 2017)Ever since their discovery, radicals have intrigued the minds of experimental and theoretical chemists alike. While the vast majority of radicals are transient species, a large number of stable and persistent radicals ...
Thermal, spectroscopic and crystallographic analysis of mannose-derived linear polyols Mattsson, Ida; Lahtinen, Manu; Peuronen, Anssi; Sau, Abhijit; Gunell, Andreas; Saloranta-Simell, Tiina; Leino, Reko (American Chemical Society, 2018)The major diastereomer formed in the Barbier-type metal-mediated allylation of D-mannose has previously been shown to adopt a perfectly linear conformation, both in solid state and in solution, resulting in the formation ...
Correlating Solution‐ and Solid‐State Structures of Conformationally Flexible Resorcinarenes : Significance of a Sulfonyl Group in Intramolecular Self‐Inclusion Pamuła, Małgorzata; Nissinen, Maija; Helttunen, Kaisa (Wiley-VCH Verlag, 2020)In this study, the synthesis of tetramethoxy resorcinarene podands bearing p‐toluene arms connected by ‐SO3‐ (1) and ‐CH2O‐ (2) linkers is presented. In the solid state, the resorcinarene podand 1 forms an intramolecular ...
Experimental and computational studies of transition metal complexes with polydentate amino- and amidophenolate ligands : synthesis, structure, reactivity and magnetic properties Hänninen, Mikko M. (University of Jyväskylä, 2013)Chelating polydentate ligands play a key role in several areas of modern coordination chemistry. They can be exploited, for example, in catalysis, bioinorganic chemistry, heavy metal abstraction and molecular magnetism. ...
Robust, Highly Luminescent Au13 Superatoms Protected by N-Heterocyclic Carbenes Narouz, Mina R.; Takano, Shinjiro; Lummis, Paul A.; Levchenko, Tetyana I.; Nazemi, Ali; Kaappa, Sami; Malola, Sami; Yousefalizadeh, Goonay; Calhoun, Larry A.; Stamplecoskie, Kevin G.; Häkkinen, Hannu; Tsukuda, Tatsuya; Crudden, Cathleen M. (American Chemical Society, 2019)Gold superatom nanoclusters stabilized entirely by N-heterocyclic carbenes (NHCs) are reported. The reduction of well-defined NHC–Au–Cl complexes produces clusters com-prised of an icosahedral Au13 core surrounded by a ...