| dc.contributor.author | Caputo, Christine | |
| dc.contributor.author | Brazeau, Allison | |
| dc.contributor.author | Hynes, Zachery | |
| dc.contributor.author | Price, Jacquelyn | |
| dc.contributor.author | Tuononen, Heikki | |
| dc.contributor.author | Jones, Nathan | |
| dc.date.accessioned | 2015-11-24T12:10:17Z | |
| dc.date.available | 2015-11-24T12:10:17Z | |
| dc.date.issued | 2009 | |
| dc.identifier.citation | Caputo, C., Brazeau, A., Hynes, Z., Price, J., Tuononen, H., & Jones, N. (2009). A Cation-Captured Palladium(0) Anion: Synthesis, Structure, and Bonding of [PdBr(PPh3)2]− Ligated by an N-Heterocyclic Phosphenium Cation. <i>Organometallics</i>, <i>28</i>(17), 5261-5265. <a href="https://doi.org/10.1021/om9006278" target="_blank">https://doi.org/10.1021/om9006278</a> | |
| dc.identifier.other | CONVID_19245578 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/47803 | |
| dc.description.abstract | Unsaturated N-heterocyclic phosphenium cations (uNHP) stabilize the [Pd0(PR3)2X]− anion proposed over the past decade to be the crucial but elusive intermediate in palladium-catalyzed cross-coupling reactions (X = halide). Insertion of metal into the P−Br bond of the precursor mesityl-substituted bromophosphine gives the structurally characterized Pd(0)-phosphenium complex (uNHPMes)Pd(PPh3)2Br, which features a long Pd−Br bond (2.7240(9) Å) and the shortest known Pd−P bond (2.1166(17) Å). The reaction is proposed to proceed by an associative pathway involving a Pd-bromophosphine complex that undergoes P-to-Pd bromide transfer. | |
| dc.language.iso | eng | |
| dc.publisher | ACS | |
| dc.relation.ispartofseries | Organometallics | |
| dc.subject.other | palladium-fosfiini -kompleksit | |
| dc.subject.other | palladium-phosphine complexes | |
| dc.title | A Cation-Captured Palladium(0) Anion: Synthesis, Structure, and Bonding of [PdBr(PPh3)2]− Ligated by an N-Heterocyclic Phosphenium Cation | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201511203749 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2015-11-20T13:15:07Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 5261-5265 | |
| dc.relation.issn | 0276-7333 | |
| dc.relation.numberinseries | 17 | |
| dc.relation.volume | 28 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © 2009 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.type.publication | article | |
| dc.relation.doi | 10.1021/om9006278 | |
| dc.type.okm | A1 | |
