dc.contributor.author | Venkateswaran, Ramalingam | |
dc.contributor.author | Balakrishna, Maravanji | |
dc.contributor.author | Mobin, Shaikh | |
dc.contributor.author | Tuononen, Heikki | |
dc.date.accessioned | 2015-11-20T09:13:05Z | |
dc.date.available | 2015-11-20T09:13:05Z | |
dc.date.issued | 2007 | |
dc.identifier.citation | Venkateswaran, R., Balakrishna, M., Mobin, S., & Tuononen, H. (2007). Copper(I) Complexes of Bis(2-(diphenylphosphino)phenyl) Ether: Synthesis, Reactivity, and Theoretical Calculations. <i>Inorganic Chemistry</i>, <i>46</i>(16), 6535-6541. <a href="https://doi.org/10.1021/ic7005474" target="_blank">https://doi.org/10.1021/ic7005474</a> | |
dc.identifier.other | CONVID_17431652 | |
dc.identifier.other | TUTKAID_28496 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/47765 | |
dc.description.abstract | The tricoordinated cationic CuI complex [Cu(κ2-P,P‘-DPEphos)(κ1-P-DPEphos)][BF4] (1) (DPEphos = bis(2-(diphenylphosphino)phenyl) ether) containing a dangling phosphorus center was synthesized from the reaction of [Cu(CH3CN)4][BF4] with DPEphos in a 1:2 molar ratio in dichloromethane. When complex 1 is treated with MnO2, elemental sulfur, or selenium, the uncoordinated phosphorus atom undergoes oxidation to form a PE bond resulting in the formation of complexes of the type [Cu(κ2-P,P‘-DPEphos)(κ2-P,E-DPEphos-E)][BF4] (2, E = O; 3, E = S; 4, E = Se) containing a Cu−E bond. The zigzag polymeric CuI complex [Cu(κ2-P,P‘-DPEphos)(μ-4,4‘-bpy)]n[BF4]n (5) was prepared by the reaction of [Cu(CH3CN)4][BF4] with DPEphos and 4,4‘-bipyridine in an equimolar ratio. The stereochemical influences of DPEphos on its coordination behavior are examined by density functional theory calculations. | |
dc.language.iso | eng | |
dc.publisher | ACS | |
dc.relation.ispartofseries | Inorganic Chemistry | |
dc.subject.other | difenyylifosfino | |
dc.subject.other | kupari(I) kompleksit | |
dc.subject.other | diphenylphosphino | |
dc.subject.other | copper(I) complex | |
dc.title | Copper(I) Complexes of Bis(2-(diphenylphosphino)phenyl) Ether: Synthesis, Reactivity, and Theoretical Calculations | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201511183711 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2015-11-18T13:15:31Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 6535-6541 | |
dc.relation.issn | 0020-1669 | |
dc.relation.numberinseries | 16 | |
dc.relation.volume | 46 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2007 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.doi | 10.1021/ic7005474 | |
dc.type.okm | A1 | |