An Unusual Ditelluride: Synthesis and Molecular and Electronic Structures of the Dimer of the Tellurium-Centered Radical [TePiPr2NiPr2PTe]•

Chivers, Tristram; Eisler, Dana; Ritch, Jamie; Tuononen, Heikki

doi:10.1002/anie.200501138

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Chivers, T., Eisler, D., Ritch, J., & Tuononen, H. (2005). An Unusual Ditelluride: Synthesis and Molecular and Electronic Structures of the Dimer of the Tellurium-Centered Radical [TePiPr2NiPr2PTe]•. Angewandte Chemie, International Edition, 44(31), 4953-4956. https://doi.org/10.1002/anie.200501138

Julkaistu sarjassa

Angewandte Chemie, International Edition

Tekijät

Chivers, Tristram |

Eisler, Dana |

Ritch, Jamie |

Tuononen, Heikki

Päivämäärä

2005

Oppiaine

Epäorgaaninen ja analyyttinen kemia Inorganic and Analytical Chemistry

Tekijänoikeudet

© 2005 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.

Facile formation of the ditelluride [(TePiPr2NiPr2PTe-)2], which exists as a centrosymmetric dimer (see picture: Te green, P purple, N blue, C gray) with a weak Te[BOND]Te bond, embodies a new feature of the chemistry of dichalcogenoimidodiphosphinate ligands. The monotelluride HPiPr2NiPr2PTe analogue is obtained as the P[BOND]H tautomer.

Julkaisija

Wiley

ISSN Hae Julkaisufoorumista

0570-0833

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