Guiding macromolecules by using magnetic tweezers
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Theoretical and computational studies of magnetic anisotropy and exchange coupling in molecular systems
Mansikkamäki, Akseli (University of Jyväskylä, 2018)The field of molecular magnetism studies the magnetic properties of molecular systems as opposed to conventional metal-based magnets. The high chemical modifiability of the constituting molecules makes such materials highly ... -
Substituent effects on exchange anisotropy in single- and multiorbital organic radical magnets
Marbey, Jonathan; Mailman, Aaron; Oakley, Richard, T.; Hill, Stephen; Winter, Stephen, M. (American Physical Society (APS), 2024)The contribution of heavy-atom substituents to the overall spin-orbit interaction in two classes of organic radical molecular magnets is discussed. In “single-orbital” radicals, spin-orbit coupling (SOC) effects are well ... -
Chirality selective spin interactions mediated by the moving superconducting condensate
Rabinovich, D. S.; Bobkova, I. V.; Bobkov, A. M.; Silaev, Mikhail (American Physical Society, 2018)We show that superconducting correlations in the presence of nonzero condensate velocity can mediate the peculiar interaction between localized spins that breaks the global inversion symmetry of magnetic moments. The proposed ... -
Dynamic Magnetic and Optical Insight into a High Performance Pentagonal Bipyramidal Dy(III) Single-Ion Magnet
Chen, Yan-Cong; Liu, Jun-Liang; Lan, Yanhua; Zhong, Zhi-Qiang; Mansikkamäki, Akseli; Ungur, Liviu; Li, Quan-Wen; Jia, Jian-Hua; Chibotaru, Liviu F.; Han, Jun-Bo; Wernsdorfer, Wolfgang; Chen, Xiao-Ming; Tong, Ming-Liang (Wiley-VCH, 2017)The pentagonal bipyramidal single-ion magnets (SIMs) are among the most attractive prototypes of high-performance single-molecule magnets (SMMs). Here, a fluorescence-active phosphine oxide ligand CyPh2PO (=cyclohexyl(di ... -
Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet
Guo, Fu-Sheng; Day, Benjamin M.; Chen, Yan-Cong; Tong, Ming-Liang; Mansikkamäki, Akseli; Layfield, Richard A. (American Association for the Advancement of Science, 2018)Single-molecule magnets (SMMs) containing only one metal center may represent the lower size limit for molecule-based magnetic information storage materials. Their current 15 drawback is that all SMMs require liquid-helium ...
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