Tiokruunueetterien metallikompleksit

Virtanen, Tiina

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Tekijät

Virtanen, Tiina

Päivämäärä

2012

Oppiaine

Orgaaninen kemia

Tämä LuK-tutkielma käsittelee tiokruunueetterien metallikomplekseja. Tarkemman tarkastelun kohteeksi on valittu pelkkiä rikkidonoreita sisältävien tiokruunueettereiden hopea-, kulta-, kupari-, palladium- ja platinakompleksit, jotka ovat lisäksi homoleptisiä eli eivät sisällä tiokruunueetterien lisäksi muita ligandeja. Tutkielmassa on keskitetty lähinnä kompleksien rakenteisiin ja koordinaatiokemiaan.

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Pyrazolium- and 1,2-Cyclopentadiene-Based Ligands as σ-Donors: a Theoretical Study of Electronic Structure and Bonding

Peuronen, Anssi; Hänninen, Mikko M.; Tuononen, Heikki (ACS, 2012)

A high-level theoretical investigation of 1,2-cyclopentadiene (4) was performed using density functional theory and wave function methods. The results reveal that, in contrast to earlier assumptions, the ground state of ...
Phospha-Fischer Carbenes: Synthesis, Structure, Bonding, and Reactions of Pd(0)− and Pt(0)−Phosphenium Complexes

Caputo, Christine; Jennings, Michael; Tuononen, Heikki; Jones, Nathan (ACS, 2009)

The analogy between cationic group 10 metal−phosphenium complexes and Fischer carbenes has been formalized through structural and reactivity studies and by energy decomposition analysis (EDA) of the M−P bond. The studied ...
Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes

Ghosh, Biswa Nath; Topic, Filip; Sahoo, Prasit Kumar; Mal, Prasenjit; Linnera, Jarno; Kalenius, Elina; Tuononen, Heikki; Rissanen, Kari (RSC Publications, 2015)

A new fluorescent terpyridyl-diphenylacetylene hybrid fluorophore 4′-[4-{(4-methoxyphenyl)ethynyl}phenyl]-2,2′:6′,2′′-terpyridine, L, was synthesized via Sonogashira cross-coupling of 4′-(4-bromophenyl)-2,2′:6′,2′′-terpyridine ...
Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2]-: structural diversity in lithium(i), zinc(ii) and nickel(ii) complexes

Thirumoorthi, Ramalingam; Chivers, Tristram; Häggman, Susanna; Mansikkamäki, Akseli; Morgan, Ian; Tuononen, Heikki; Lahtinen, Manu; Konu, Jari (RSC Publications, 2016)

A high-yield synthesis of [Li{S(H)C(PPh2S)2}]2 [Li2·(3)2] was developed and this reagent was used in metathesis with ZnCl2 and NiCl2 to produce homoleptic complexes 4 and 5b in 85 and 93% yields, respectively. The solid-state ...
Synthesis, X-ray structures and redox behaviour of the group 14 bis-boraamidinates M[PhB(μ-N-t-Bu)2]2 (M = Ge, Sn) and Li2M[PhB(μ-N-t-Bu)2]2 (M = Sn, Pb)

Konu, Jari; Tuononen, Heikki; Chivers, Tristram (NRC Research Press, 2009)

The solid-state structures of the complexes M[PhB(μ-N-t-Bu)2]2 (1a, M= Ge; 1b, M = Sn) were determined to be spirocyclic with two orthogonal boraamidinate (bam) ligands N,N′-chelated to the group 14 centre. Oxidation of ...

Tiokruunueetterien metallikompleksit

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Pyrazolium- and 1,2-Cyclopentadiene-Based Ligands as σ-Donors: a Theoretical Study of Electronic Structure and Bonding ﻿

Phospha-Fischer Carbenes: Synthesis, Structure, Bonding, and Reactions of Pd(0)− and Pt(0)−Phosphenium Complexes ﻿

Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes ﻿

Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2]-: structural diversity in lithium(i), zinc(ii) and nickel(ii) complexes ﻿

Synthesis, X-ray structures and redox behaviour of the group 14 bis-boraamidinates M[PhB(μ-N-t-Bu)2]2 (M = Ge, Sn) and Li2M[PhB(μ-N-t-Bu)2]2 (M = Sn, Pb) ﻿

Pyrazolium- and 1,2-Cyclopentadiene-Based Ligands as σ-Donors: a Theoretical Study of Electronic Structure and Bonding

Phospha-Fischer Carbenes: Synthesis, Structure, Bonding, and Reactions of Pd(0)− and Pt(0)−Phosphenium Complexes

Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes

Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2]-: structural diversity in lithium(i), zinc(ii) and nickel(ii) complexes

Synthesis, X-ray structures and redox behaviour of the group 14 bis-boraamidinates M[PhB(μ-N-t-Bu)2]2 (M = Ge, Sn) and Li2M[PhB(μ-N-t-Bu)2]2 (M = Sn, Pb)