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dc.contributor.authorPeuronen, Anssi
dc.contributor.authorTaponen, Anni
dc.contributor.authorKalenius, Elina
dc.contributor.authorLehtonen, Ari
dc.contributor.authorLahtinen, Manu
dc.date.accessioned2023-02-07T08:35:58Z
dc.date.available2023-02-07T08:35:58Z
dc.date.issued2023
dc.identifier.citationPeuronen, A., Taponen, A., Kalenius, E., Lehtonen, A., & Lahtinen, M. (2023). Charge‐Assisted Halogen Bonding in an Ionic Cavity of a Coordination Cage Based on a Copper(I) Iodide Cluster. <i>Angewandte Chemie</i>, <i>62</i>(7), Article e202215689. <a href="https://doi.org/10.1002/anie.202215689" target="_blank">https://doi.org/10.1002/anie.202215689</a>
dc.identifier.otherCONVID_164744160
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/85387
dc.description.abstractThe design of molecular containers capable of selective binding of specific guest molecules presents an interesting synthetic challenge in supramolecular chemistry. Here, we report the synthesis and structure of a coordination cage assembled from Cu3I4– clusters and tripodal cationic N-donor ligands. Owing to the localized permanent charges in the ligand core the cage binds iodide anions in specific regions within the cage by ionic interactions. This allows the selective binding of bromomethanes as secondary guest species within cage promoted by halogen bonding, which was confirmed by single crystal X-ray diffraction.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesAngewandte Chemie
dc.rightsCC BY 4.0
dc.subject.otherkoordinaatiohäkit
dc.subject.othercoordination cage
dc.subject.othercluster compounds
dc.subject.otherhalogen bond
dc.subject.otherhost-guest systems
dc.titleCharge‐Assisted Halogen Bonding in an Ionic Cavity of a Coordination Cage Based on a Copper(I) Iodide Cluster
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202302071667
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen kemiafi
dc.contributor.oppiaineResurssiviisausyhteisöfi
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineAnalyyttinen kemiafi
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineInorganic Chemistryen
dc.contributor.oppiaineSchool of Resource Wisdomen
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineAnalytical Chemistryen
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.relation.issn1433-7851
dc.relation.numberinseries7
dc.relation.volume62
dc.type.versionpublishedVersion
dc.rights.copyright© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber277250
dc.subject.ysokupari
dc.subject.ysohalogeenit
dc.subject.ysokemialliset sidokset
dc.subject.ysojodi
dc.subject.ysosupramolekulaarinen kemia
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p19074
jyx.subject.urihttp://www.yso.fi/onto/yso/p4164
jyx.subject.urihttp://www.yso.fi/onto/yso/p10130
jyx.subject.urihttp://www.yso.fi/onto/yso/p18902
jyx.subject.urihttp://www.yso.fi/onto/yso/p37759
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1002/anie.202215689
dc.relation.funderResearch Council of Finlanden
dc.relation.funderSuomen Akatemiafi
jyx.fundingprogramAcademy Project, AoFen
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundinginformationAP and ML gratefully acknowledge the financial support from the Academy of Finland (no. 315911 and 277250, respectively).
dc.type.okmA1


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