Azoniafluorenones : A New Family of Two‐Electron Storage Electrolytes for Sustainable Near‐Neutral pH Aqueous Organic Flow Battery

Abstract

Fluorenones are suitable candidates for negolytes in flow batteries, as they demonstrate the ability to store 2 electrons, and can achieve reversibility, solubility, and stability with appropriate molecular design. However, limitations persist such as the use of alkaline media, high redox potentials, and a limited scope for optimization. Herein, azoniafluorenones is reported as a novel class of negolytes. They can be readily accessed in a highly modular fashion from inexpensive commercially available materials (e.g., boronicacids). Variations in the substitution patterns reveal the 3-substituted N-alkylated AZON3, which demonstrates excellent solubility at neutral pH (1.64 m) with two low reversible redox potentials (−0.31 and −0.58 V vs Ag/AgCl). AZON3 exhibits high stability when evaluated at high concentration in a neutral supporting electrolyte (1 m in 3 m KCl), paired with BTMAP-Fc on the positive side. Capacity retentions of 99.95% and 99.91% per cycle (99.35% and 99.21% per day) are achieved when cycling with 1 and 2 electrons, respectively, coupled with high volumetric capacity of 46.4 Ah L−1 (87% of capacity utilization).