Spodium bonding in bis(alkynyl)mecurials
Abstract
The new bis(alkynyl)mercurial Hg{C[triple bond, length as m-dash]CSeC[triple bond, length as m-dash]W(CO)2(Tp*)}2 (Tp* = tris(dimethylpyrazolyl)borate) forms adducts with fluoride and phenathroline, the structures of which are interpreted in the context of two-coordinate mercury presenting a σ-torroid for spodium bonding.
Main Authors
Format
Articles
Research article
Published
2024
Series
Subjects
Publication in research information system
Publisher
Royal Society of Chemistry
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-202403222573Käytä tätä linkitykseen.
Review status
Peer reviewed
ISSN
1359-7345
DOI
https://doi.org/10.1039/D3CC06027F
Language
English
Published in
Chemical Communications
Citation
- Onn, C. S., Hill, A. F., & Ward, J. S. (2024). Spodium bonding in bis(alkynyl)mecurials. Chemical Communications, 60(18), 2552-2555. https://doi.org/10.1039/D3CC06027F
License
Additional information about funding
We gratefully acknowledge the Australian Research Council (DP200101222 and DP230199215) for funding.
Copyright© 2024 Royal Society of Chemistry