Synthesis, characterisation and reactivity of a zinc triazenide for potential use in vapour deposition
Samii, R., Barkas, E., Zanders, D., Fransson, A., Lahtinen, M., Kessler, V., Tuononen, H. M., Moilanen, J. O., & O'Brien, N. J. (2024). Synthesis, characterisation and reactivity of a zinc triazenide for potential use in vapour deposition. Dalton Transactions, 53(13), 5911-5916. https://doi.org/10.1039/D4DT00084F
Published in
Dalton TransactionsAuthors
Date
2024Discipline
Epäorgaaninen ja analyyttinen kemiaNanoscience CenterEpäorgaaninen kemiaResurssiviisausyhteisöInorganic and Analytical ChemistryNanoscience CenterInorganic ChemistrySchool of Resource WisdomCopyright
© 2024 The Royal Society of Chemistry
In this study, we synthesised and characterised a new zinc(II) triazenide for potential use in vapour deposition of zinc sulphide thin films. The compound is volatile and quantitatively sublimes at 80 °C under vacuum (0.5 mbar). Thermogravimetric analysis showed a one-step volatilisation with an onset temperature at ∼125 °C and 5% residual mass. The compound also reacted with 2 or 4 molar equivalents of triphenylsilanethiol to give dimeric and monomeric zinc thiolates, respectively. The high volatility, thermal stability, and reactivity with sterically hindered thiols makes this compound a potential candidate for use in vapour deposition of zinc containing thin films.
Publisher
Royal Society of ChemistryISSN Search the Publication Forum
1477-9226Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/207584626
Metadata
Show full item recordCollections
Related funder(s)
Research Council of FinlandFunding program(s)
Academy Research Fellow, AoF; Academy Project, AoFAdditional information about funding
The project was funded by the Swedish Foundation for Strategic Research through the project “Time-resolved low temperature CVD for III-nitrides” (SSF-RMA 15-0018) and by the Knut and Alice Wallenberg foundation through the project “Bridging the THz gap” (No. KAW 2013.0049). E. B. and J. O. M. acknowledge the Research Council of Finland (projects 315829 and 338733) for financial support.License
Related items
Showing items with similar title or keywords.
-
Synthesis, X-ray Structure, Cytotoxic, and Anti-Microbial Activities of Zn(II) Complexes with a Hydrazono s-Triazine Bearing Pyridyl Arm
Hassan, MennaAllah; El-Faham, Ayman; Barakat, Assem; Haukka, Matti; Tatikonda, Rajendhraprasad; Abu-Youssef, Morsy A. M.; Soliman, Saied M.; Yousri, Amal (MDPI, 2024)The [ZnL(ONO2)2] 1 and [ZnL(NCS)2] 2 complexes were synthesized using self-assembly of the s-triazine tridentate ligand (L) with Zn(NO3)2·6H2O and Zn(ClO4)2·6H2O/NH4SCN, respectively. The Zn(II) is further coordinated by ... -
Atomic Layer Deposition of Zinc Oxide on Mesoporous Zirconia Using Zinc(II) Acetylacetonate and Air
Yim, Jihong; Haimi, Eero; Mäntymäki, Miia; Kärkäs, Ville; Bes, René; Gutierrez, Aitor Arandia; Meinander, Kristoffer; Brüner, Philipp; Grehl, Thomas; Gell, Lars; Viinikainen, Tiia; Honkala, Karoliina; Huotari, Simo; Karinen, Reetta; Putkonen, Matti; Puurunen, Riikka L. (American Chemical Society, 2023)The self-terminating chemistry of atomic layer deposition (ALD) ideally enables the growth of homogeneously distributed materials on the atomic scale. This study investigates the ALD of zinc oxide (ZnO) on mesoporous ... -
Deterministic Modification of CVD Grown Monolayer MoS2 with Optical Pulses
Turunen, Mikko T.; Hulkko, Eero; Mentel, Kamila K.; Bai, Xueyin; Akkanen, Suvi‐Tuuli; Amini, Mohammad; Li, Shisheng; Lipsanen, Harri; Pettersson, Mika; Sun, Zhipei (Wiley-VCH Verlag, 2021)Transition metal dichalcogenide monolayers have demonstrated a number of exquisite optical and electrical properties. Here, the authors report the optical modification of topographical and optical properties of monolayer ... -
The Difficult Marriage of Triarylcorroles with Zinc and Nickel Ions
Naitana, Mario L.; Osterloh, W. Ryan; Di Zazzo, Lorena; Nardis, Sara; Caroleo, Fabrizio; Stipa, Pierluigi; Truong, Khai-Nghi; Rissanen, Kari; Fang, Yuanyuan; Kadish, Karl M.; Paolesse, Roberto (American Chemical Society (ACS), 2022)The coordination chemistry of corrole has witnessed a great improvement in the past few years and its Periodic Table has been widened to be so large that it is compared with that of porphyrins. However, Ni and Zn ions, ... -
3D Zinc–Organic Frameworks Based on Mixed Thiophene Dicarboxylate and 4-Amino-3,5-bis(4-pyridyl)-1,2,4-triazole Linkers : Syntheses, Structural Diversity, and Single-Crystal-to-Single-Crystal Transformations
Mahajan, Shreya; Lahtinen, Manu (American Chemical Society (ACS), 2024)In this study, for the first time two new interpenetrated 3D pillared-layer metal–organic frameworks (MOFs), namely, {[Zn(bpt)(tdc)]·dmf}n (MOF-1-Zn) and {[Zn2(bpt)(tdc)2]·2(dmf)}n (MOF-2-Zn), as well as a homochiral 3D ...