Cavity-induced bifurcation in classical rate theory

Abstract
We show how coupling an ensemble of bistable systems to a common cavity field affects the collective stochastic behavior of this ensemble. In particular, the cavity provides an effective interaction between the systems, and parametrically modifies the transition rates between the metastable states. We predict that the cavity induces a phase transition at a critical temperature which depends linearly on the number of systems. It shows up as a spontaneous symmetry breaking where the stationary states of the bistable system bifurcate. We observe that the transition rates slow down independently of the phase transition, but the rate modification vanishes for alternating signs of the system-cavity couplings, corresponding to a disordered ensemble of dipoles. Our results are of particular relevance in polaritonic chemistry where the presence of a cavity has been suggested to affect chemical reactions.
Main Authors
Format
Articles Research article
Published
2024
Series
Subjects
Publication in research information system
Publisher
SciPost Foundation
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-202401311670Käytä tätä linkitykseen.
Review status
Peer reviewed
ISSN
2542-4653
DOI
https://doi.org/10.21468/scipostphys.16.1.025
Language
English
Published in
SciPost Physics
Citation
License
CC BY 4.0Open Access
Additional information about funding
Funders for the research work leading to this publication: Suomen Akatemia / Academy of Finland, Magnus Ehrnroothin Säätiö
Copyright© K. S. U. Kansanen and T. T. Heikkilä.

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