Laskennalliset verot eri tilinpäätösnormistoissa : case: Gardner Denver Oy
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Stable spirocyclic neutral radicals: aluminum and gallium boraamidinates
Chivers, Tristram; Eisler, Dana; Fedorchuk, Chantall; Schatte, Gabriele; Tuononen, Heikki; Boeré, René (RSC, 2005)Stable dark red (M = Al) or dark green (M = Ga) neutral radicals {[PhB(μ-NtBu)2]2M}˙ are obtained by the oxidation of their corresponding anions with iodine, and EPR spectra supported by DFT calculations show that the spin ... -
1-Phenyl-3-(pyrid-2-yl)benzo[e][1,2,4]triazinyl: The First “Blatter Radical” for Coordination Chemistry
Morgan, Ian; Peuronen, Anssi; Hänninen, Mikko M.; Reed, Robert; Clerac, Rodolphe; Tuononen, Heikki (American Chemical Society, 2014)A neutral air- and moisture-stable N,N′-chelating radical ligand, 1-phenyl-3-(pyrid-2-yl)benzo[e][1,2,4]triazinyl (1) was synthesized and characterized by electron paramagnetic resonance spectroscopy, X-ray crystallography, ... -
Isolation of a Stable, Acyclic, Two-Coordinate Silylene
Rekken, Brian; Brown, Thomas; Fettinger, James; Tuononen, Heikki; Power, Philip (ACS, 2012)The synthesis and characterization of a stable, acyclic two-coordinate silylene, Si(SArMe6)2, (ArMe6 = C6H3-2,6(C6H2-2,4,6-Me3)2) by reduction of Br2Si(SArMe6)2 with a magnesium(I) reductant is described. It features ... -
Paramagnetic aluminium β-diketiminate
Moilanen, Jani; Borau-Garcia, Javier; Roesler, Roland; Tuononen, Heikki (RSC, 2012)The β-diketiminate ligand framework is shown to undergo reduction to form a neutral main group radical stabilized by spiroconjugation of the unpaired electron over the group 13 element centre. The synthesized paramagnetic ...